TY - JOUR
T1 - Graphene edges and beyond
T2 - Temperature-driven structures and electromagnetic properties
AU - Hyun, Changbae
AU - Yun, Jeonghun
AU - Cho, Woo Jong
AU - Myung, Chang Woo
AU - Park, Jaesung
AU - Lee, Geunsik
AU - Lee, Zonghoon
AU - Kim, Kwanpyo
AU - Kim, Kwang S.
N1 - Publisher Copyright:
© 2015 American Chemical Society.
Copyright:
Copyright 2015 Elsevier B.V., All rights reserved.
PY - 2015/5/26
Y1 - 2015/5/26
N2 - The atomic configuration of graphene edges significantly influences the various properties of graphene nanostructures, and realistic device fabrication requires precise engineering of graphene edges. However, the imaging and analysis of the intrinsic nature of graphene edges can be illusive due to contamination problems and measurement-induced structural changes to graphene edges. In this issue of ACS Nano, He et al. report an in situ heating experiment in aberration-corrected transmission electron microscopy to elucidate the temperature dependence of graphene edge termination at the atomic scale. They revealed that graphene edges predominantly have zigzag terminations below 400 °C, while above 600 °C, the edges are dominated by armchair and reconstructed zigzag edges. This report brings us one step closer to the true nature of graphene edges. In this Perspective, we outline the present understanding, issues, and future challenges faced in the field of graphene-edge-based nanodevices.
AB - The atomic configuration of graphene edges significantly influences the various properties of graphene nanostructures, and realistic device fabrication requires precise engineering of graphene edges. However, the imaging and analysis of the intrinsic nature of graphene edges can be illusive due to contamination problems and measurement-induced structural changes to graphene edges. In this issue of ACS Nano, He et al. report an in situ heating experiment in aberration-corrected transmission electron microscopy to elucidate the temperature dependence of graphene edge termination at the atomic scale. They revealed that graphene edges predominantly have zigzag terminations below 400 °C, while above 600 °C, the edges are dominated by armchair and reconstructed zigzag edges. This report brings us one step closer to the true nature of graphene edges. In this Perspective, we outline the present understanding, issues, and future challenges faced in the field of graphene-edge-based nanodevices.
UR - http://www.scopus.com/inward/record.url?scp=84930670995&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84930670995&partnerID=8YFLogxK
U2 - 10.1021/acsnano.5b02617
DO - 10.1021/acsnano.5b02617
M3 - Review article
AN - SCOPUS:84930670995
VL - 9
SP - 4669
EP - 4674
JO - ACS Nano
JF - ACS Nano
SN - 1936-0851
IS - 5
ER -