Graphene multilayer supported gold nanoparticles for efficient electrocatalysts toward methanol oxidation

Yuri Choi, Minsu Gu, Jongnam Park, Hyun Kon Song, Byeong-Su Kim

Research output: Contribution to journalArticle

45 Citations (Scopus)

Abstract

This study reports a simple method of integrating electroactive gold nanoparticles (Au NPs) with graphene oxide (GO) nanosheet support by layer-by-layer (LbL) assembly for the creation of 3-dimensional electrocatalytic thin films that are active toward methanol oxidation. This approach involves the alternating assembly of two oppositely charged suspensions of Au NPs with GO nanosheets based on electrostatic interactions. The GO nanosheets not only serve as structural components of the multilayer thin film, but also potentially improve the utilization and dispersion of Au NPs by taking advantages of the high catalytic surface area and the electronic conduction of graphene nanosheets. Furthermore, it is found that the electrocatalytic activity of the multilayer thin films of Au NPs with graphene nanosheet is highly tunable with respect to the number of bilayers and thermal treatment, benefiting from the advantageous features of LbL assembly. Because of the highly versatile and tunable properties of LbL assembled thin films coupled with electrocatalytic NPs, we anticipate that the general concept presented here will offer new types of electroactive catalysts for direct methanol fuel cells.

Original languageEnglish
Pages (from-to)1510-1518
Number of pages9
JournalAdvanced Energy Materials
Volume2
Issue number12
DOIs
Publication statusPublished - 2012 Dec 1

Fingerprint

Graphite
Nanosheets
Electrocatalysts
Gold
Graphene
Methanol
Multilayers
Nanoparticles
Oxidation
Oxides
Thin films
Multilayer films
Direct methanol fuel cells (DMFC)
Coulomb interactions
Suspensions
Heat treatment
Catalysts

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

Cite this

Choi, Yuri ; Gu, Minsu ; Park, Jongnam ; Song, Hyun Kon ; Kim, Byeong-Su. / Graphene multilayer supported gold nanoparticles for efficient electrocatalysts toward methanol oxidation. In: Advanced Energy Materials. 2012 ; Vol. 2, No. 12. pp. 1510-1518.
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Graphene multilayer supported gold nanoparticles for efficient electrocatalysts toward methanol oxidation. / Choi, Yuri; Gu, Minsu; Park, Jongnam; Song, Hyun Kon; Kim, Byeong-Su.

In: Advanced Energy Materials, Vol. 2, No. 12, 01.12.2012, p. 1510-1518.

Research output: Contribution to journalArticle

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