Graphene Phototransistors Sensitized by Cu2-xSe Nanocrystals with Short Amine Ligands

Juhee Lee, Yuseong Gim, Jeehye Yang, Hyunwoo Jo, Jaehun Han, Hojin Lee, Do Hwan Kim, Wansoo Huh, Jeong Ho Cho, Moon Sung Kang

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Recent attempts to employ colloidal semiconductor nanocrystals (NCs) as the sensitizing materials for hybrid NC-graphene phototransistors have provided a new effective photosensing platform. However, most of these devices are based on NCs containing either lead or cadmium, which would not be the most preferred material candidates for commercialization. Here, we demonstrate the use of colloidal Cu2-xSe NCs that do not contain lead or cadmium as the sensitizers for NCs-graphene hybrid visible phototransistors. Because the long olyelamine ligands originally attached on Cu2-xSe NCs are known to impede electronic process between NCs and graphene, the long ligands are replaced with short amines including octylamine, hexylamine, and butylamine. It is found that the NCs layer with shorter amine ligands yields a more prominent n-doping effect on graphene under illumination, which results in a systematic negative shift in Dirac voltage. More importantly, this leads to devices with larger photocurrent and larger light responsivity. Consequently, from Cu2-xSe NC-graphene hybrid phototransistors attached with butylamine ligands, responsivity as high as 2600 A/W and photocurrent gain as high as 36 000 are achieved at an optical power of 5 × 10-8 W, which are expected be even larger at lower optical powers. (Figure Presented).

Original languageEnglish
Pages (from-to)5436-5443
Number of pages8
JournalJournal of Physical Chemistry C
Volume121
Issue number9
DOIs
Publication statusPublished - 2017 Mar 9

Fingerprint

Phototransistors
phototransistors
Graphite
Nanocrystals
Graphene
Amines
amines
nanocrystals
graphene
Ligands
ligands
Butylamines
Photocurrents
Cadmium
cadmium
photocurrents
Lead
sensitizing
commercialization
platforms

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Energy(all)
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films

Cite this

Lee, Juhee ; Gim, Yuseong ; Yang, Jeehye ; Jo, Hyunwoo ; Han, Jaehun ; Lee, Hojin ; Kim, Do Hwan ; Huh, Wansoo ; Cho, Jeong Ho ; Kang, Moon Sung. / Graphene Phototransistors Sensitized by Cu2-xSe Nanocrystals with Short Amine Ligands. In: Journal of Physical Chemistry C. 2017 ; Vol. 121, No. 9. pp. 5436-5443.
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Lee, J, Gim, Y, Yang, J, Jo, H, Han, J, Lee, H, Kim, DH, Huh, W, Cho, JH & Kang, MS 2017, 'Graphene Phototransistors Sensitized by Cu2-xSe Nanocrystals with Short Amine Ligands', Journal of Physical Chemistry C, vol. 121, no. 9, pp. 5436-5443. https://doi.org/10.1021/acs.jpcc.7b01212

Graphene Phototransistors Sensitized by Cu2-xSe Nanocrystals with Short Amine Ligands. / Lee, Juhee; Gim, Yuseong; Yang, Jeehye; Jo, Hyunwoo; Han, Jaehun; Lee, Hojin; Kim, Do Hwan; Huh, Wansoo; Cho, Jeong Ho; Kang, Moon Sung.

In: Journal of Physical Chemistry C, Vol. 121, No. 9, 09.03.2017, p. 5436-5443.

Research output: Contribution to journalArticle

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AU - Gim, Yuseong

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AU - Kang, Moon Sung

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