Graphene-Selenium Hybrid Microballs as Cathode Materials for High-performance Lithium-Selenium Secondary Battery Applications

Hee Chang Youn, Jun Hui Jeong, Kwang Chul Roh, Kwang Bum Kim

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

In this study, graphene-selenium hybrid microballs (G-SeHMs) are prepared in one step by aerosol microdroplet drying using a commercial spray dryer, which represents a simple, scalable continuous process, and the potential of the G-SeHMs thus prepared is investigated for use as cathode material in applications of lithium-selenium secondary batteries. These morphologically unique graphene microballs filled with Se particles exhibited good electrochemical properties, such as high initial specific capacity (642 mA h g-1 at 0.1 C, corresponding to Se electrochemical utilisation as high as 95.1%), good cycling stability (544 mA h g-1 after 100 cycles at 0.1 C; 84.5% retention) and high rate capability (specific capacity of 301 mA h g-1 at 5C). These electrochemical properties are attributed to the fact that the G-SeHM structure acts as a confinement matrix for suppressing the dissolution of polyselenides in the organic electrolyte, as well as an electron conduction path for increasing the transport rate of electrons for electrochemical reactions. Notably, based on the weight of hybrid materials, electrochemical performance is considerably better than that of previously reported Se-based cathode materials, attributed to the high Se loading content (80 wt%) in hybrid materials.

Original languageEnglish
Article number30865
JournalScientific reports
Volume6
DOIs
Publication statusPublished - 2016 Aug 2

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Selenium
Lithium
Electrodes
Electron Transport
Aerosols
Electrolytes
Electrons
Weights and Measures

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Cite this

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abstract = "In this study, graphene-selenium hybrid microballs (G-SeHMs) are prepared in one step by aerosol microdroplet drying using a commercial spray dryer, which represents a simple, scalable continuous process, and the potential of the G-SeHMs thus prepared is investigated for use as cathode material in applications of lithium-selenium secondary batteries. These morphologically unique graphene microballs filled with Se particles exhibited good electrochemical properties, such as high initial specific capacity (642 mA h g-1 at 0.1 C, corresponding to Se electrochemical utilisation as high as 95.1{\%}), good cycling stability (544 mA h g-1 after 100 cycles at 0.1 C; 84.5{\%} retention) and high rate capability (specific capacity of 301 mA h g-1 at 5C). These electrochemical properties are attributed to the fact that the G-SeHM structure acts as a confinement matrix for suppressing the dissolution of polyselenides in the organic electrolyte, as well as an electron conduction path for increasing the transport rate of electrons for electrochemical reactions. Notably, based on the weight of hybrid materials, electrochemical performance is considerably better than that of previously reported Se-based cathode materials, attributed to the high Se loading content (80 wt{\%}) in hybrid materials.",
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Graphene-Selenium Hybrid Microballs as Cathode Materials for High-performance Lithium-Selenium Secondary Battery Applications. / Youn, Hee Chang; Jeong, Jun Hui; Roh, Kwang Chul; Kim, Kwang Bum.

In: Scientific reports, Vol. 6, 30865, 02.08.2016.

Research output: Contribution to journalArticle

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