Graphene Transistors Gated by Salted Proton Conductor

Hyunwoo Kim, Beom Joon Kim, Qijun Sun, Moon Sung Kang, Jeong Ho Cho

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The first use of proton conductors for gating graphene transistors is demonstrated. The proton conductor used in this study, [poly(styrenesulfonic acid)], is added with sodium halide salts in order to improve the capacitive characteristics of the electrolyte gate dielectric. The influence of the added sodium halide salts (NaF, NaCl, NaBr, and NaI), the salt concentration, and the relative humidity on the dielectric properties of the electrolyte are investigated systematically. Substantial enhancement in the device performances of the graphene transistors including carrier mobility, device ON current, Dirac voltage, and device cut-off frequency is attained with the addition of the sodium halide salts. From the optimized conditions based on NaI salts, the graphene transistors exhibit hole and electron mobilities of 1900 and 990 cm2 V–1 s–1, respectively, with Dirac voltage near 0 V. Moreover, the cut-off frequency of the device presenting the dynamic characteristics of a transistor reach up to 100 kHz.

Original languageEnglish
Article number1600122
JournalAdvanced Electronic Materials
Volume2
Issue number8
DOIs
Publication statusPublished - 2016 Aug 1

Fingerprint

Protons
Salts
Sodium
Cutoff frequency
Electrolytes
Hole mobility
Electron mobility
Gate dielectrics
Carrier mobility
Electric potential
Dielectric properties
Atmospheric humidity
Transistors
Graphene transistors
Acids

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials

Cite this

Kim, Hyunwoo ; Kim, Beom Joon ; Sun, Qijun ; Kang, Moon Sung ; Cho, Jeong Ho. / Graphene Transistors Gated by Salted Proton Conductor. In: Advanced Electronic Materials. 2016 ; Vol. 2, No. 8.
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Graphene Transistors Gated by Salted Proton Conductor. / Kim, Hyunwoo; Kim, Beom Joon; Sun, Qijun; Kang, Moon Sung; Cho, Jeong Ho.

In: Advanced Electronic Materials, Vol. 2, No. 8, 1600122, 01.08.2016.

Research output: Contribution to journalArticle

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AB - The first use of proton conductors for gating graphene transistors is demonstrated. The proton conductor used in this study, [poly(styrenesulfonic acid)], is added with sodium halide salts in order to improve the capacitive characteristics of the electrolyte gate dielectric. The influence of the added sodium halide salts (NaF, NaCl, NaBr, and NaI), the salt concentration, and the relative humidity on the dielectric properties of the electrolyte are investigated systematically. Substantial enhancement in the device performances of the graphene transistors including carrier mobility, device ON current, Dirac voltage, and device cut-off frequency is attained with the addition of the sodium halide salts. From the optimized conditions based on NaI salts, the graphene transistors exhibit hole and electron mobilities of 1900 and 990 cm2 V–1 s–1, respectively, with Dirac voltage near 0 V. Moreover, the cut-off frequency of the device presenting the dynamic characteristics of a transistor reach up to 100 kHz.

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