Green synthesis of AgI-reduced graphene oxide nanocomposites: Toward enhanced visible-light photocatalytic activity for organic dye removal

D. Amaranatha Reddy, Seunghee Lee, Jiha Choi, Seonhwa Park, Rory Ma, Haesik Yang, Tae Kyu Kim

Research output: Contribution to journalArticlepeer-review

85 Citations (Scopus)


Novel reduced graphene oxide (RGO) enwrapped AgI nanocomposites were successfully fabricated by a facile template-free ultrasound-assisted method at room temperature. The structural, morphological, and optical studies demonstrate that the obtained nanostructures have good crystallinity and that the graphene nanosheets are decorated densely with AgI nanostructures. The photocatalytic activity of the composite was evaluated by the degradation of an organic dye, Rhodamine B (RhB), under visible-light irradiation. The results indicate that AgI with incorporated graphene exhibited much higher photocatalytic activity than the pure AgI due to the improved separation efficiency of the photogenerated carriers and that it prolonged the lifetime of the electron-hole pairs due to the chemical bonding between AgI and graphene. AgI (0.4 mg mL -1 of graphene oxide) nanocomposites displayed the highest photocatalytic degradation efficiency and the corresponding catalytic efficiencies within 70 min were ∼96%. Moreover, with the assistance of H 2 O 2 the photocatalytic ability of the as-obtained AgI-RGO nanocomposites was enhanced. The corresponding catalytic efficiencies within 30 min were ∼96.8% (for 1 mL H 2 O 2 ) under the same irradiation conditions. The excellent visible-light photocatalytic efficiency and luminescence properties make the AgI-RGO nanocomposites promising candidates for the removal of organic dyes for water purification and enable their application in near-UV white LEDs.

Original languageEnglish
Pages (from-to)175-184
Number of pages10
JournalApplied Surface Science
Publication statusPublished - 2015 Jun 30

Bibliographical note

Funding Information:
This work was financially supported by National Research Foundation of Korea (NRF) grants, funded by the Korean government (MEST and MSIP) (2013S1A2A2035406, 2013R1A1A2009575 and 2014R1A4A1001690). This work also supported by Max Planck POSTECH/KOREA Research Initiative Program [Grant No. 2011-0031558 ] through the National Research Foundation of Korea (NRF) funded by Ministry of Science, ICT and Future Planning .

Publisher Copyright:
© 2015 Elsevier B.V. All rights reserved.

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Condensed Matter Physics
  • Physics and Astronomy(all)
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films


Dive into the research topics of 'Green synthesis of AgI-reduced graphene oxide nanocomposites: Toward enhanced visible-light photocatalytic activity for organic dye removal'. Together they form a unique fingerprint.

Cite this