Halide perovskite nanopillar photodetector

Do Hyung Chun, Young Jin Choi, Yongjae In, Jae Keun Nam, Yung Ji Choi, Sangeun Yun, Wook Kim, Dukhyun Choi, Dongho Kim, Hyunjung Shin, Jeong Ho Cho, Jong Hyeok Park

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Numerous studies have reported the use of halide perovskites as highly functional light-harvesting materials. The development of optimized compositions and deposition approaches has led to impressive improvements; however, no noticeable breakthrough in performance has been observed for these materials recently. Here, a breakthrough that enables the fabrication of vertically grown halide perovskite (VGHP) nanopillar photodetectors via a nanoimprinting crystallization technique is demonstrated. We used engraved nanopatterned polymer stamps to form VGHP nanopillars during the pressurized crystallization of the softly baked gel state of a methylammonium lead iodide (CH3NH3PbI3, denoted MAPI) film. The VGHP films exhibit much lower defect density and higher conductivity, as supported by current-voltage characteristic measurements and conductive atomic force microscopy measurements. Ultimately, two-terminal lateral photodetectors based on the VGHP nanopillar films show a greatly enhanced photoresponse compared with flat film-based photodetectors. We expect that the deposition method presented here will help surpass the technical limits and contribute to further improvements in various halide-perovskite-based devices.

Original languageEnglish
Pages (from-to)8564-8571
Number of pages8
JournalACS Nano
Volume12
Issue number8
DOIs
Publication statusPublished - 2018 Aug 28

Fingerprint

Photodetectors
Perovskite
halides
photometers
Crystallization
crystallization
Defect density
Iodides
Current voltage characteristics
perovskites
Atomic force microscopy
Polymers
Gels
iodides
Lead
perovskite
Fabrication
atomic force microscopy
gels
conductivity

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Engineering(all)
  • Physics and Astronomy(all)

Cite this

Chun, D. H., Choi, Y. J., In, Y., Nam, J. K., Choi, Y. J., Yun, S., ... Park, J. H. (2018). Halide perovskite nanopillar photodetector. ACS Nano, 12(8), 8564-8571. https://doi.org/10.1021/acsnano.8b04170
Chun, Do Hyung ; Choi, Young Jin ; In, Yongjae ; Nam, Jae Keun ; Choi, Yung Ji ; Yun, Sangeun ; Kim, Wook ; Choi, Dukhyun ; Kim, Dongho ; Shin, Hyunjung ; Cho, Jeong Ho ; Park, Jong Hyeok. / Halide perovskite nanopillar photodetector. In: ACS Nano. 2018 ; Vol. 12, No. 8. pp. 8564-8571.
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Chun, DH, Choi, YJ, In, Y, Nam, JK, Choi, YJ, Yun, S, Kim, W, Choi, D, Kim, D, Shin, H, Cho, JH & Park, JH 2018, 'Halide perovskite nanopillar photodetector', ACS Nano, vol. 12, no. 8, pp. 8564-8571. https://doi.org/10.1021/acsnano.8b04170

Halide perovskite nanopillar photodetector. / Chun, Do Hyung; Choi, Young Jin; In, Yongjae; Nam, Jae Keun; Choi, Yung Ji; Yun, Sangeun; Kim, Wook; Choi, Dukhyun; Kim, Dongho; Shin, Hyunjung; Cho, Jeong Ho; Park, Jong Hyeok.

In: ACS Nano, Vol. 12, No. 8, 28.08.2018, p. 8564-8571.

Research output: Contribution to journalArticle

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Chun DH, Choi YJ, In Y, Nam JK, Choi YJ, Yun S et al. Halide perovskite nanopillar photodetector. ACS Nano. 2018 Aug 28;12(8):8564-8571. https://doi.org/10.1021/acsnano.8b04170