This study demonstrates the first reported thermocatalytic oxidation of an indoor volatile organic compound (VOC), acetaldehyde, by harnessing the waste-heat energy from indoor light sources (e.g., halogen lamps) without additional energy inputs. With an optimal Pt–TiO2 catalyst, the designed catalyst-coated lampshade was successfully activated under waste-heat energy (∼120 °C) and achieved the complete mineralization of CH3CHO into CO2 (k = 0.02 min−1). The catalytic activity of Pt–TiO2 was extremely dependent on its preparation method which greatly influenced the characteristics (e.g., oxidation state and size) of Pt. The thermocatalytic oxidation mechanism of CH3CHO over Pt–TiO2 was investigated, which revealed that O2 and H2O sources play vital roles. Although Pt is an expensive noble metal, the thermocatalytic process on the Pt–TiO2-coated lampshade without additional energy, along with its outstanding activity, can offset the high material cost. The proposed strategy offers a sustainable and feasible method for the degradation of indoor VOCs.
|Publication status||Published - 2022 Dec|
Bibliographical noteFunding Information:
This work was supported by the National Research Foundation of Korea ( 2021R1C1C1007706 , 2022R1A4A1021692 ), the Korea Agency for Infrastructure Technology Advancement (KAIA) grant funded by the Ministry of Land, Infrastructure and Transport (Grant 21CTAP-C157292-02 ), the Ecological Imitation-based Environmental Pollution Management Technology Development Project ( 2019002790008 ) funded by the Korea Ministry of Environment (MOE), and development of nano product performance, and safety evaluation technology and company support project through the Ministry of Trade, Industry and Energy (MOTIE) (Project No. 20015633 ).
All Science Journal Classification (ASJC) codes
- Environmental Engineering
- Environmental Chemistry
- Public Health, Environmental and Occupational Health
- Health, Toxicology and Mutagenesis