Helically foldable diphenylureas as anion receptors: Modulation of the binding affinity by the chain length

Min Jung Kim, Hye Won Lee, Dohyun Moon, Kyu Sung Jeong

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

Using a series of diphenylureas capable of folding to helical conformations, the binding trends have been compared between two anions of different sizes, chloride and sulfate. The binding constant for the sulfate ion steadily increases from monomer to pentamer as the chain length increases, but for the chloride ion it increases up until the trimer and then reaches a plateau.

Original languageEnglish
Pages (from-to)5042-5045
Number of pages4
JournalOrganic Letters
Volume14
Issue number19
DOIs
Publication statusPublished - 2012 Oct 5

Fingerprint

Chain length
Sulfates
Anions
affinity
Chlorides
sulfates
chlorides
Modulation
Ions
anions
modulation
trimers
folding
Conformations
plateaus
ions
monomers
Monomers
trends

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

Cite this

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Helically foldable diphenylureas as anion receptors : Modulation of the binding affinity by the chain length. / Kim, Min Jung; Lee, Hye Won; Moon, Dohyun; Jeong, Kyu Sung.

In: Organic Letters, Vol. 14, No. 19, 05.10.2012, p. 5042-5045.

Research output: Contribution to journalArticle

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