Hematite modified tungsten trioxide nanoparticle photoanode for solar water oxidation

Aiming Mao, Jung Kyu Kim, Kahee Shin, Dong Hwan Wang, Pil J. Yoo, Gui Young Han, Jong Hyeok Park

Research output: Contribution to journalArticle

39 Citations (Scopus)

Abstract

Hematite (α-Fe 2O 3) film is electrochemically deposited onto the surface of tungsten trioxide (WO 3) nanoparticulate film. The synthesis of the WO 3 nanostructure is directed by surfactants for control of its morphology. The resulting composite shows visible light harvesting and is tested as photoanodes in heterojunction photoelectrochemical cells for the possibility of direct water splitting under visible illumination. The composite's structural and optical properties are characterized by FESEM, EDS, XRD, XPS, and UV-vis spectrometry; its photocurrent responses are also investigated under simulated solar illumination. Coupling WO 3 with hematite results in over 9 times greater photocurrent density than that shown by pure WO 3 in sodium sulfate electrolyte. This simple modification can significantly improve the performance of WO 3.

Original languageEnglish
Pages (from-to)32-37
Number of pages6
JournalJournal of Power Sources
Volume210
DOIs
Publication statusPublished - 2012 Jul 15

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Energy Engineering and Power Technology
  • Physical and Theoretical Chemistry
  • Electrical and Electronic Engineering

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