Heterostructure Engineering of a Reverse Water Gas Shift Photocatalyst

Hong Wang, Jia Jia, Lu Wang, Keith Butler, Rui Song, Gilberto Casillas, Le He, Nazir P. Kherani, Doug D. Perovic, Liqiang Jing, Aron Walsh, Roland Dittmeyer, Geoffrey A. Ozin

Research output: Contribution to journalArticle

Abstract

To achieve substantial reductions in CO2 emissions, catalysts for the photoreduction of CO2 into value-added chemicals and fuels will most likely be at the heart of key renewable-energy technologies. Despite tremendous efforts, developing highly active and selective CO2 reduction photocatalysts remains a great challenge. Herein, a metal oxide heterostructure engineering strategy that enables the gas-phase, photocatalytic, heterogeneous hydrogenation of CO2 to CO with high performance metrics (i.e., the conversion rate of CO2 to CO reached as high as 1400 µmol g cat−1 h−1) is reported. The catalyst is comprised of indium oxide nanocrystals, In2O3− x(OH)y, nucleated and grown on the surface of niobium pentoxide (Nb2O5) nanorods. The heterostructure between In2O3− x(OH)y nanocrystals and the Nb2O5 nanorod support increases the concentration of oxygen vacancies and prolongs excited state (electron and hole) lifetimes. Together, these effects result in a dramatically improved photocatalytic performance compared to the isolated In2O3− x(OH)y material. The defect optimized heterostructure exhibits a 44-fold higher conversion rate than pristine In2O3− x(OH)y. It also exhibits selective conversion of CO2 to CO as well as long-term operational stability.

Original languageEnglish
Article number1902170
JournalAdvanced Science
Volume6
Issue number22
DOIs
Publication statusPublished - 2019 Nov 1

Fingerprint

Water gas shift
Carbon Monoxide
Photocatalysts
Heterojunctions
Nanotubes
Gases
engineering
Nanorods
Nanoparticles
Nanocrystals
nanorods
Water
shift
nanocrystals
gases
Renewable Energy
water
energy technology
catalysts
Catalysts

All Science Journal Classification (ASJC) codes

  • Medicine (miscellaneous)
  • Chemical Engineering(all)
  • Biochemistry, Genetics and Molecular Biology (miscellaneous)
  • Materials Science(all)
  • Engineering(all)
  • Physics and Astronomy(all)

Cite this

Wang, H., Jia, J., Wang, L., Butler, K., Song, R., Casillas, G., ... Ozin, G. A. (2019). Heterostructure Engineering of a Reverse Water Gas Shift Photocatalyst. Advanced Science, 6(22), [1902170]. https://doi.org/10.1002/advs.201902170
Wang, Hong ; Jia, Jia ; Wang, Lu ; Butler, Keith ; Song, Rui ; Casillas, Gilberto ; He, Le ; Kherani, Nazir P. ; Perovic, Doug D. ; Jing, Liqiang ; Walsh, Aron ; Dittmeyer, Roland ; Ozin, Geoffrey A. / Heterostructure Engineering of a Reverse Water Gas Shift Photocatalyst. In: Advanced Science. 2019 ; Vol. 6, No. 22.
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Wang, H, Jia, J, Wang, L, Butler, K, Song, R, Casillas, G, He, L, Kherani, NP, Perovic, DD, Jing, L, Walsh, A, Dittmeyer, R & Ozin, GA 2019, 'Heterostructure Engineering of a Reverse Water Gas Shift Photocatalyst', Advanced Science, vol. 6, no. 22, 1902170. https://doi.org/10.1002/advs.201902170

Heterostructure Engineering of a Reverse Water Gas Shift Photocatalyst. / Wang, Hong; Jia, Jia; Wang, Lu; Butler, Keith; Song, Rui; Casillas, Gilberto; He, Le; Kherani, Nazir P.; Perovic, Doug D.; Jing, Liqiang; Walsh, Aron; Dittmeyer, Roland; Ozin, Geoffrey A.

In: Advanced Science, Vol. 6, No. 22, 1902170, 01.11.2019.

Research output: Contribution to journalArticle

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AU - Wang, Hong

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AU - Wang, Lu

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AU - Casillas, Gilberto

AU - He, Le

AU - Kherani, Nazir P.

AU - Perovic, Doug D.

AU - Jing, Liqiang

AU - Walsh, Aron

AU - Dittmeyer, Roland

AU - Ozin, Geoffrey A.

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Wang H, Jia J, Wang L, Butler K, Song R, Casillas G et al. Heterostructure Engineering of a Reverse Water Gas Shift Photocatalyst. Advanced Science. 2019 Nov 1;6(22). 1902170. https://doi.org/10.1002/advs.201902170