High adsorption of ethylene by alkali-treated halloysite nanotubes for food-packaging applications

Kirtiraj K. Gaikwad, Suman Singh, Youn Suk Lee

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Fresh food products such as fruits and vegetables are usually degrading fast after harvest, notably due to the production of ethylene, an aging hormone, by the products. Therefore, ethylene adsorbents in the form of powders are commonly used in packaging to maintain the postharvest quality of fresh products. The use of naturally-based adsorbents is preferred for safe food-packaging applications. Here we studied halloysite nanotubes as natural ethylene scavengers. We tested the effect of storage conditions on the kinetics of ethylene adsorption. Raw halloysite nanotubes were subjected to alkaline treatment to increase their pore size. We compared the efficacy of raw halloysite nanotubes versus alkaline halloysite nanotubes. Materials were characterized by Fourier transform infrared spectroscopy, thermogravimetric analysis, and transmission electron microscopy. Results show that alkali-treated halloysite nanotubes have the highest ethylene adsorption capacity at 11% relative humidity and 23 °C. The ethylene adsorption kinetics data were slightly fitted to a pseudo-first-order model, and the rate constant of the ethylene adsorption was 0.7107 min−1. After 24 h, 49 μL of ethylene gas present in headspace was removed with 1 g of alkali halloysite nanotubes.

Original languageEnglish
Pages (from-to)1055-1062
Number of pages8
JournalEnvironmental Chemistry Letters
Volume16
Issue number3
DOIs
Publication statusPublished - 2018 Sep 1

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halloysite
Alkalies
Nanotubes
ethylene
Packaging
adsorption
Adsorption
food
Adsorbents
kinetics
Kinetics
clay
packaging
nanotube
Vegetables
scavenger
Fruits
FTIR spectroscopy
Powders
vegetable

All Science Journal Classification (ASJC) codes

  • Environmental Chemistry

Cite this

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abstract = "Fresh food products such as fruits and vegetables are usually degrading fast after harvest, notably due to the production of ethylene, an aging hormone, by the products. Therefore, ethylene adsorbents in the form of powders are commonly used in packaging to maintain the postharvest quality of fresh products. The use of naturally-based adsorbents is preferred for safe food-packaging applications. Here we studied halloysite nanotubes as natural ethylene scavengers. We tested the effect of storage conditions on the kinetics of ethylene adsorption. Raw halloysite nanotubes were subjected to alkaline treatment to increase their pore size. We compared the efficacy of raw halloysite nanotubes versus alkaline halloysite nanotubes. Materials were characterized by Fourier transform infrared spectroscopy, thermogravimetric analysis, and transmission electron microscopy. Results show that alkali-treated halloysite nanotubes have the highest ethylene adsorption capacity at 11{\%} relative humidity and 23 °C. The ethylene adsorption kinetics data were slightly fitted to a pseudo-first-order model, and the rate constant of the ethylene adsorption was 0.7107 min−1. After 24 h, 49 μL of ethylene gas present in headspace was removed with 1 g of alkali halloysite nanotubes.",
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High adsorption of ethylene by alkali-treated halloysite nanotubes for food-packaging applications. / Gaikwad, Kirtiraj K.; Singh, Suman; Lee, Youn Suk.

In: Environmental Chemistry Letters, Vol. 16, No. 3, 01.09.2018, p. 1055-1062.

Research output: Contribution to journalArticle

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