High-Performance Green Light-Emitting Diodes Based on MAPbBr3-Polymer Composite Films Prepared by Gas-Assisted Crystallization

Yun Cheol Kim, Yoann Porte, Sung Doo Baek, Seong Rae Cho, Jae Min Myoung

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

The morphology of perovskite films has a significant impact on luminous characteristics of perovskite light-emitting diodes (PeLEDs). To obtain a highly uniform methylammonium lead tribromide (MAPbBr3) film, a gas-assisted crystallization method is introduced with a mixed solution of MAPbBr3 precursor and polymer matrix. The ultrafast evaporation of the solvent causes a high degree of supersaturation which expedites the generation of a large number of nuclei to form a MAPbBr3-polymer composite film with full surface coverage and nano-sized grains. The addition of the polymer matrix significantly affects the optical properties and morphology of MAPbBr3 films. The PeLED made of the MAPbBr3-polymer composite film exhibits an outstanding device performance of a maximum luminance of 6800 cd·m-2 and a maximum current efficiency of 1.12 cd·A-1. Furthermore, 1 cm2 area pixel of PeLED displays full coverage of a strong green electroluminescence, implying that the high-quality perovskite film can be useful for large-area applications in perovskite-based optoelectronic devices.

Original languageEnglish
Pages (from-to)44106-44113
Number of pages8
JournalACS Applied Materials and Interfaces
Volume9
Issue number50
DOIs
Publication statusPublished - 2017 Dec 20

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Composite films
Crystallization
Polymer films
Perovskite
Light emitting diodes
Gases
Polymer matrix
Supersaturation
Electroluminescence
Optoelectronic devices
perovskite
Luminance
Evaporation
Optical properties
Lead
Pixels

All Science Journal Classification (ASJC) codes

  • Materials Science(all)

Cite this

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High-Performance Green Light-Emitting Diodes Based on MAPbBr3-Polymer Composite Films Prepared by Gas-Assisted Crystallization. / Kim, Yun Cheol; Porte, Yoann; Baek, Sung Doo; Cho, Seong Rae; Myoung, Jae Min.

In: ACS Applied Materials and Interfaces, Vol. 9, No. 50, 20.12.2017, p. 44106-44113.

Research output: Contribution to journalArticle

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