High-Performance Green Light-Emitting Diodes Based on MAPbBr3 with π-Conjugated Ligand

Hee Ju An; Yun Cheol Kim; Do Hoon Kim; Jae Min Myoung

doi:10.1021/acsami.0c02923

High-Performance Green Light-Emitting Diodes Based on MAPbBr₃ with π-Conjugated Ligand

Hee Ju An, Yun Cheol Kim, Do Hoon Kim, Jae Min Myoung

Department of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The morphology, crystal size, and trap density of perovskite films significantly affect the luminescent properties of perovskite light-emitting diodes (PeLEDs). Recently, numerous studies have been conducted on ligands that surround the surface of perovskite crystals and passivate the trap sites to improve the performance of PeLEDs. In this study, a 4-aminobenzonitrile (ABN) ligand improved the performance of methylammonium lead bromide (MAPbBr₃)-based PeLEDs by reducing the MAPbBr₃ crystal size to the nanoscale and reducing the trap density. Moreover, the properties of PeLEDs with ABN were further improved using a surface-modified hole-transport layer (HTL) with a hydrophilic polymer. Finally, a bright green PeLED was fabricated, which exhibited the maximum luminance of 3350 cd/m² with an external quantum efficiency of 8.85%. Therefore, it is believed that the use of proper ligands for the perovskite layer and the optimization of the charge-transport layer have great potential for the development of high-performance PeLEDs.

Original language	English
Pages (from-to)	16726-16735
Number of pages	10
Journal	ACS Applied Materials and Interfaces
Volume	12
Issue number	14
DOIs	https://doi.org/10.1021/acsami.0c02923
Publication status	Published - 2020 Apr 8

Bibliographical note

Funding Information:
This work was supported by the Samsung Research Funding & Incubation Center of Samsung Electronics under Project Number SRFC-MA1901-01.

Publisher Copyright:
Copyright © 2020 American Chemical Society.

All Science Journal Classification (ASJC) codes

Materials Science(all)

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title = "High-Performance Green Light-Emitting Diodes Based on MAPbBr3 with π-Conjugated Ligand",

abstract = "The morphology, crystal size, and trap density of perovskite films significantly affect the luminescent properties of perovskite light-emitting diodes (PeLEDs). Recently, numerous studies have been conducted on ligands that surround the surface of perovskite crystals and passivate the trap sites to improve the performance of PeLEDs. In this study, a 4-aminobenzonitrile (ABN) ligand improved the performance of methylammonium lead bromide (MAPbBr3)-based PeLEDs by reducing the MAPbBr3 crystal size to the nanoscale and reducing the trap density. Moreover, the properties of PeLEDs with ABN were further improved using a surface-modified hole-transport layer (HTL) with a hydrophilic polymer. Finally, a bright green PeLED was fabricated, which exhibited the maximum luminance of 3350 cd/m2 with an external quantum efficiency of 8.85%. Therefore, it is believed that the use of proper ligands for the perovskite layer and the optimization of the charge-transport layer have great potential for the development of high-performance PeLEDs.",

author = "An, {Hee Ju} and Kim, {Yun Cheol} and Kim, {Do Hoon} and Myoung, {Jae Min}",

note = "Funding Information: This work was supported by the Samsung Research Funding & Incubation Center of Samsung Electronics under Project Number SRFC-MA1901-01. Publisher Copyright: Copyright {\textcopyright} 2020 American Chemical Society.",

year = "2020",

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AU - Kim, Yun Cheol

AU - Kim, Do Hoon

AU - Myoung, Jae Min

N1 - Funding Information: This work was supported by the Samsung Research Funding & Incubation Center of Samsung Electronics under Project Number SRFC-MA1901-01. Publisher Copyright: Copyright © 2020 American Chemical Society.

PY - 2020/4/8

Y1 - 2020/4/8

N2 - The morphology, crystal size, and trap density of perovskite films significantly affect the luminescent properties of perovskite light-emitting diodes (PeLEDs). Recently, numerous studies have been conducted on ligands that surround the surface of perovskite crystals and passivate the trap sites to improve the performance of PeLEDs. In this study, a 4-aminobenzonitrile (ABN) ligand improved the performance of methylammonium lead bromide (MAPbBr3)-based PeLEDs by reducing the MAPbBr3 crystal size to the nanoscale and reducing the trap density. Moreover, the properties of PeLEDs with ABN were further improved using a surface-modified hole-transport layer (HTL) with a hydrophilic polymer. Finally, a bright green PeLED was fabricated, which exhibited the maximum luminance of 3350 cd/m2 with an external quantum efficiency of 8.85%. Therefore, it is believed that the use of proper ligands for the perovskite layer and the optimization of the charge-transport layer have great potential for the development of high-performance PeLEDs.

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