High-reversible capacity of Perovskite BaSnO3/rGO composite for Lithium-Ion Battery Anodes

Ganapathy Veerappan; SunyoungYoo; Kan Zhang; Ming Ma; Byoungwoo Kang; Jong Hyeok Park

doi:10.1016/j.electacta.2016.07.076

High-reversible capacity of Perovskite BaSnO₃/rGO composite for Lithium-Ion Battery Anodes

Ganapathy Veerappan, SunyoungYoo, Kan Zhang, Ming Ma, Byoungwoo Kang, Jong Hyeok Park

Department of Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

To the best of our knowledge, this is first report about composite of perovskite materials and reduced graphene oxide as anode material for high performance lithium ion battery (LIB). Here, we report outstanding specific capacities and cyclic stabilities of perovskite BaSnO₃ nanoparticles (NPs), decorated on 2D graphene sheets. Electrochemical measurements show that the composite BaSnO₃/rGO20 (20 wt.%rGO) delivered a highest capacity of 1200 mAh g⁻¹ at a current rate of 0.5C (650 mA g⁻¹), which is comparatively much higher than individual pristine BaSnO₃ and graphene anodes. The BaSnO₃/rGO composite anode exhibits a very high rate capability even at the 10C discharge rate (1059 mAh g⁻¹) and outstanding long-term stability. Notably, the composite anode material maintains its discharge capacity even after 100 cycles.

Original language	English
Pages (from-to)	31-37
Number of pages	7
Journal	Electrochimica Acta
Volume	214
DOIs	https://doi.org/10.1016/j.electacta.2016.07.076
Publication status	Published - 2016 Oct 1

Bibliographical note

Funding Information:
This work was supported by the NRF of Korea Grant funded by the Ministry of Science, ICT & Future Planning (NRF-2013R1A2A1A09014038, 2012R1A1A2044697).

Publisher Copyright:
© 2016 Elsevier Ltd

All Science Journal Classification (ASJC) codes

Chemical Engineering(all)
Electrochemistry

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This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.electacta.2016.07.076

Cite this

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title = "High-reversible capacity of Perovskite BaSnO3/rGO composite for Lithium-Ion Battery Anodes",

abstract = "To the best of our knowledge, this is first report about composite of perovskite materials and reduced graphene oxide as anode material for high performance lithium ion battery (LIB). Here, we report outstanding specific capacities and cyclic stabilities of perovskite BaSnO3 nanoparticles (NPs), decorated on 2D graphene sheets. Electrochemical measurements show that the composite BaSnO3/rGO20 (20 wt.%rGO) delivered a highest capacity of 1200 mAh g−1 at a current rate of 0.5C (650 mA g−1), which is comparatively much higher than individual pristine BaSnO3 and graphene anodes. The BaSnO3/rGO composite anode exhibits a very high rate capability even at the 10C discharge rate (1059 mAh g−1) and outstanding long-term stability. Notably, the composite anode material maintains its discharge capacity even after 100 cycles.",

author = "Ganapathy Veerappan and SunyoungYoo and Kan Zhang and Ming Ma and Byoungwoo Kang and Park, {Jong Hyeok}",

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AU - Veerappan, Ganapathy

AU - SunyoungYoo,

AU - Zhang, Kan

AU - Ma, Ming

AU - Kang, Byoungwoo

AU - Park, Jong Hyeok

N1 - Funding Information: This work was supported by the NRF of Korea Grant funded by the Ministry of Science, ICT & Future Planning (NRF-2013R1A2A1A09014038, 2012R1A1A2044697). Publisher Copyright: © 2016 Elsevier Ltd

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N2 - To the best of our knowledge, this is first report about composite of perovskite materials and reduced graphene oxide as anode material for high performance lithium ion battery (LIB). Here, we report outstanding specific capacities and cyclic stabilities of perovskite BaSnO3 nanoparticles (NPs), decorated on 2D graphene sheets. Electrochemical measurements show that the composite BaSnO3/rGO20 (20 wt.%rGO) delivered a highest capacity of 1200 mAh g−1 at a current rate of 0.5C (650 mA g−1), which is comparatively much higher than individual pristine BaSnO3 and graphene anodes. The BaSnO3/rGO composite anode exhibits a very high rate capability even at the 10C discharge rate (1059 mAh g−1) and outstanding long-term stability. Notably, the composite anode material maintains its discharge capacity even after 100 cycles.

AB - To the best of our knowledge, this is first report about composite of perovskite materials and reduced graphene oxide as anode material for high performance lithium ion battery (LIB). Here, we report outstanding specific capacities and cyclic stabilities of perovskite BaSnO3 nanoparticles (NPs), decorated on 2D graphene sheets. Electrochemical measurements show that the composite BaSnO3/rGO20 (20 wt.%rGO) delivered a highest capacity of 1200 mAh g−1 at a current rate of 0.5C (650 mA g−1), which is comparatively much higher than individual pristine BaSnO3 and graphene anodes. The BaSnO3/rGO composite anode exhibits a very high rate capability even at the 10C discharge rate (1059 mAh g−1) and outstanding long-term stability. Notably, the composite anode material maintains its discharge capacity even after 100 cycles.

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