Abstract
A series of isostructural M-MOF-74 materials (M = Mg, Co, and Zn) with proper pore sizes (11 Å) and highly dense unsaturated metal sites have been examined for the selective adsorption of SF6 over nitrogen. Mg-MOF-74 and Co-MOF-74 show the largest SF6 uptake reported for any adsorbent, including MOFs, at ambient temperature and pressure. Zn-MOF-74 exhibits one of the highest SF6/N2 reported selectivities. These materials were evaluated for two possible SF6 separation processes using five adsorbent criteria, revealing that these materials are promising adsorptive materials for SF6/N2 separation.
| Original language | English |
|---|---|
| Pages (from-to) | 356-361 |
| Number of pages | 6 |
| Journal | Microporous and Mesoporous Materials |
| Volume | 190 |
| DOIs | |
| Publication status | Published - 2014 May 15 |
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All Science Journal Classification (ASJC) codes
- Chemistry(all)
- Materials Science(all)
- Condensed Matter Physics
- Mechanics of Materials
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High SF6 selectivities and capacities in isostructural metal-organic frameworks with proper pore sizes and highly dense unsaturated metal sites. / Kim, Min Bum; Lee, Seung Joon; Lee, Chang Yeon; Bae, Youn-Sang.
In: Microporous and Mesoporous Materials, Vol. 190, 15.05.2014, p. 356-361.Research output: Contribution to journal › Article
TY - JOUR
T1 - High SF6 selectivities and capacities in isostructural metal-organic frameworks with proper pore sizes and highly dense unsaturated metal sites
AU - Kim, Min Bum
AU - Lee, Seung Joon
AU - Lee, Chang Yeon
AU - Bae, Youn-Sang
PY - 2014/5/15
Y1 - 2014/5/15
N2 - A series of isostructural M-MOF-74 materials (M = Mg, Co, and Zn) with proper pore sizes (11 Å) and highly dense unsaturated metal sites have been examined for the selective adsorption of SF6 over nitrogen. Mg-MOF-74 and Co-MOF-74 show the largest SF6 uptake reported for any adsorbent, including MOFs, at ambient temperature and pressure. Zn-MOF-74 exhibits one of the highest SF6/N2 reported selectivities. These materials were evaluated for two possible SF6 separation processes using five adsorbent criteria, revealing that these materials are promising adsorptive materials for SF6/N2 separation.
AB - A series of isostructural M-MOF-74 materials (M = Mg, Co, and Zn) with proper pore sizes (11 Å) and highly dense unsaturated metal sites have been examined for the selective adsorption of SF6 over nitrogen. Mg-MOF-74 and Co-MOF-74 show the largest SF6 uptake reported for any adsorbent, including MOFs, at ambient temperature and pressure. Zn-MOF-74 exhibits one of the highest SF6/N2 reported selectivities. These materials were evaluated for two possible SF6 separation processes using five adsorbent criteria, revealing that these materials are promising adsorptive materials for SF6/N2 separation.
UR - http://www.scopus.com/inward/record.url?scp=84896372192&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84896372192&partnerID=8YFLogxK
U2 - 10.1016/j.micromeso.2014.02.028
DO - 10.1016/j.micromeso.2014.02.028
M3 - Article
AN - SCOPUS:84896372192
VL - 190
SP - 356
EP - 361
JO - Microporous and Mesoporous Materials
JF - Microporous and Mesoporous Materials
SN - 1387-1811
ER -