High temperature strength and oxidation behaviour of hot-pressed silicon nitride-disilicate ceramics

Heon-Jin Choi, June Gunn Lee, Young Wook Kim

Research output: Contribution to journalArticle

86 Citations (Scopus)

Abstract

Twelve different silicon nitride-disilicate ceramics have been fabricated by hot-pressing Si3N4 with the oxides of Y, Yb, Ho, Dy, Er, Sm, Ce, Lu, La, Pr, Gd, and Sc that are used as sintering additives. The high temperature strength and oxidation behaviour of the hot-pressed ceramics were investigated and correlated with the cationic radii of the oxide additives. The flexural strength at 1200°C increased, from 666 MPa for Si3N4-La2Si2O7 to 965 M Pa for Si3N4-Sc2Si2O7 which is correlated with a decreasing cationic radius of the oxide additive. The weight gain during oxidation at 1400°C for 192 h in air decreased, from 0.8732mgcm-2 for a Si3N4-Sm2Si2O7 ceramic to 0.1089mgcm-2 for a Si3N4-Sc2Si2O7 ceramic, which is a function of the decreasing cationic radius of the oxide additive.

Original languageEnglish
Pages (from-to)1937-1942
Number of pages6
JournalJournal of Materials Science
Volume32
Issue number7
DOIs
Publication statusPublished - 1997 Jan 1

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Silicon nitride
Oxidation
Oxides
Temperature
Hot pressing
Bending strength
Sintering
silicon nitride
Air

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

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abstract = "Twelve different silicon nitride-disilicate ceramics have been fabricated by hot-pressing Si3N4 with the oxides of Y, Yb, Ho, Dy, Er, Sm, Ce, Lu, La, Pr, Gd, and Sc that are used as sintering additives. The high temperature strength and oxidation behaviour of the hot-pressed ceramics were investigated and correlated with the cationic radii of the oxide additives. The flexural strength at 1200°C increased, from 666 MPa for Si3N4-La2Si2O7 to 965 M Pa for Si3N4-Sc2Si2O7 which is correlated with a decreasing cationic radius of the oxide additive. The weight gain during oxidation at 1400°C for 192 h in air decreased, from 0.8732mgcm-2 for a Si3N4-Sm2Si2O7 ceramic to 0.1089mgcm-2 for a Si3N4-Sc2Si2O7 ceramic, which is a function of the decreasing cationic radius of the oxide additive.",
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High temperature strength and oxidation behaviour of hot-pressed silicon nitride-disilicate ceramics. / Choi, Heon-Jin; Lee, June Gunn; Kim, Young Wook.

In: Journal of Materials Science, Vol. 32, No. 7, 01.01.1997, p. 1937-1942.

Research output: Contribution to journalArticle

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