High temperature thermoelectric properties of Sr and Fe doped SmCoO 3 perovskite structure

Kwang Hee Jung; Soon Mok Choi; Hyung Ho Park; Won Seon Seo

doi:10.1016/j.cap.2010.12.032

High temperature thermoelectric properties of Sr and Fe doped SmCoO ₃ perovskite structure

Kwang Hee Jung, Soon Mok Choi, Hyung Ho Park, Won Seon Seo

Department of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

Sm_1-xSr_xCo_1-yFe_yO₃ specimens with perovskite structures were prepared by a solid-state reaction to investigate their high temperature thermoelectric properties. The crystal structures of Sm_1-xSr_xCo_1-yFe_yO ₃ polycrystalline samples were investigated by means of an X-ray diffraction method. All specimens showed p-type semiconducting behaviors and their electrical conductivity (σ), Seebeck coefficient (α), thermal conductivity (k) and ZT were measured at high temperatures. Effects of dopant ions on their thermoelectrical properties were also investigated. An acceptor-doping effect and distortion of the perovskite structure exerted an influence on the carrier concentration. Fe³⁺ ion doped into Co ³⁺ site enhanced the Seebeck coefficient and decreased the electrical conductivity simultaneously. On the contrary Sr²⁺ ion doped into Sm³⁺ site enhanced the electrical conductivity and decreased the Seebeck coefficient simultaneously. However heavy-doped cases (>10 mol%) caused a negative effect on the power factor values. The maximum power factor of this system, 2.0410^-4 W/mK² at 786 K was comparable to that of Ca₃Co₄O₉ system.

Original language	English
Pages (from-to)	S260-S265
Journal	Current Applied Physics
Volume	11
Issue number	3 SUPPL.
DOIs	https://doi.org/10.1016/j.cap.2010.12.032
Publication status	Published - 2011 May

Bibliographical note

Funding Information:
This work was supported by ‘ Energy Efficiency and Resources ( 2008EID11P060000 ) of KETEP R&D Program’ and by a ‘Fundamental R&D Program for Core Technology of Materials’ grant funded by the Ministry of Knowledge Economy, Republic of Korea .

All Science Journal Classification (ASJC) codes

Materials Science(all)
Physics and Astronomy(all)

Access to Document

10.1016/j.cap.2010.12.032

Cite this

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title = "High temperature thermoelectric properties of Sr and Fe doped SmCoO 3 perovskite structure",

abstract = "Sm1-xSrxCo1-yFeyO3 specimens with perovskite structures were prepared by a solid-state reaction to investigate their high temperature thermoelectric properties. The crystal structures of Sm1-xSrxCo1-yFeyO 3 polycrystalline samples were investigated by means of an X-ray diffraction method. All specimens showed p-type semiconducting behaviors and their electrical conductivity (σ), Seebeck coefficient (α), thermal conductivity (k) and ZT were measured at high temperatures. Effects of dopant ions on their thermoelectrical properties were also investigated. An acceptor-doping effect and distortion of the perovskite structure exerted an influence on the carrier concentration. Fe3+ ion doped into Co 3+ site enhanced the Seebeck coefficient and decreased the electrical conductivity simultaneously. On the contrary Sr2+ ion doped into Sm3+ site enhanced the electrical conductivity and decreased the Seebeck coefficient simultaneously. However heavy-doped cases (>10 mol%) caused a negative effect on the power factor values. The maximum power factor of this system, 2.0410-4 W/mK2 at 786 K was comparable to that of Ca3Co4O9 system.",

author = "Jung, {Kwang Hee} and Choi, {Soon Mok} and Park, {Hyung Ho} and Seo, {Won Seon}",

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AU - Jung, Kwang Hee

AU - Choi, Soon Mok

AU - Park, Hyung Ho

AU - Seo, Won Seon

N1 - Funding Information: This work was supported by ‘ Energy Efficiency and Resources ( 2008EID11P060000 ) of KETEP R&D Program’ and by a ‘Fundamental R&D Program for Core Technology of Materials’ grant funded by the Ministry of Knowledge Economy, Republic of Korea .

PY - 2011/5

Y1 - 2011/5

N2 - Sm1-xSrxCo1-yFeyO3 specimens with perovskite structures were prepared by a solid-state reaction to investigate their high temperature thermoelectric properties. The crystal structures of Sm1-xSrxCo1-yFeyO 3 polycrystalline samples were investigated by means of an X-ray diffraction method. All specimens showed p-type semiconducting behaviors and their electrical conductivity (σ), Seebeck coefficient (α), thermal conductivity (k) and ZT were measured at high temperatures. Effects of dopant ions on their thermoelectrical properties were also investigated. An acceptor-doping effect and distortion of the perovskite structure exerted an influence on the carrier concentration. Fe3+ ion doped into Co 3+ site enhanced the Seebeck coefficient and decreased the electrical conductivity simultaneously. On the contrary Sr2+ ion doped into Sm3+ site enhanced the electrical conductivity and decreased the Seebeck coefficient simultaneously. However heavy-doped cases (>10 mol%) caused a negative effect on the power factor values. The maximum power factor of this system, 2.0410-4 W/mK2 at 786 K was comparable to that of Ca3Co4O9 system.

AB - Sm1-xSrxCo1-yFeyO3 specimens with perovskite structures were prepared by a solid-state reaction to investigate their high temperature thermoelectric properties. The crystal structures of Sm1-xSrxCo1-yFeyO 3 polycrystalline samples were investigated by means of an X-ray diffraction method. All specimens showed p-type semiconducting behaviors and their electrical conductivity (σ), Seebeck coefficient (α), thermal conductivity (k) and ZT were measured at high temperatures. Effects of dopant ions on their thermoelectrical properties were also investigated. An acceptor-doping effect and distortion of the perovskite structure exerted an influence on the carrier concentration. Fe3+ ion doped into Co 3+ site enhanced the Seebeck coefficient and decreased the electrical conductivity simultaneously. On the contrary Sr2+ ion doped into Sm3+ site enhanced the electrical conductivity and decreased the Seebeck coefficient simultaneously. However heavy-doped cases (>10 mol%) caused a negative effect on the power factor values. The maximum power factor of this system, 2.0410-4 W/mK2 at 786 K was comparable to that of Ca3Co4O9 system.

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