Selected metal ions (Ni, Co, Mn, Mg, or Zn) were introduced into iron oxide (spinel lattice) and the resulting materials screened for catalytic activity for the high temperature water–gas shift reaction using waste-derived syngas. The active phase of spinel ferrite catalysts was directly synthesized by the glycine assisted sol–gel combustion method under a reducing atmosphere. Among the prepared catalysts, NiFe2O4 catalyst showed the highest CO conversion (81%) with stability even at a very high gas hourly space velocity of 40,057 h−1. This result was primarily due to the inverse spinel structure and easier reducibility of NiFe2O4 catalyst.
Bibliographical noteFunding Information:
This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT and Future Planning ( 2013R1A1A1A05007370 ).
© 2016 Hydrogen Energy Publications, LLC.
All Science Journal Classification (ASJC) codes
- Renewable Energy, Sustainability and the Environment
- Fuel Technology
- Condensed Matter Physics
- Energy Engineering and Power Technology