Highly efficient O-silylation of alcohol with vinylsilane using a Rh(l)/HCl catalyst at room temperature

Jung Woo Park; Chul Ho Jun

doi:10.1021/ol701909e

Highly efficient O-silylation of alcohol with vinylsilane using a Rh(l)/HCl catalyst at room temperature

Jung Woo Park, Chul Ho Jun

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

Highly efficient O-silylation of alcohol with vinylsilane was developed using a catalyst system consisting of [(COE)₂RhCl]₂ and HCl. In this reaction, a key intermediate is chlorosilane, generated from vinylsilane and HCl, which can be regenerated in the catalytic cycle. Various alcohols and vinylsilanes were applied to the preparation of silyl ether compounds with this catalyst system.

Original language	English
Pages (from-to)	4073-4076
Number of pages	4
Journal	Organic Letters
Volume	9
Issue number	20
DOIs	https://doi.org/10.1021/ol701909e
Publication status	Published - 2007 Sept 27

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol701909e

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abstract = "Highly efficient O-silylation of alcohol with vinylsilane was developed using a catalyst system consisting of [(COE)2RhCl]2 and HCl. In this reaction, a key intermediate is chlorosilane, generated from vinylsilane and HCl, which can be regenerated in the catalytic cycle. Various alcohols and vinylsilanes were applied to the preparation of silyl ether compounds with this catalyst system.",

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AB - Highly efficient O-silylation of alcohol with vinylsilane was developed using a catalyst system consisting of [(COE)2RhCl]2 and HCl. In this reaction, a key intermediate is chlorosilane, generated from vinylsilane and HCl, which can be regenerated in the catalytic cycle. Various alcohols and vinylsilanes were applied to the preparation of silyl ether compounds with this catalyst system.

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Highly efficient O-silylation of alcohol with vinylsilane using a Rh(l)/HCl catalyst at room temperature

Abstract

All Science Journal Classification (ASJC) codes

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