Highly efficient O-silylation of alcohol with vinylsilane using a Rh(l)/HCl catalyst at room temperature

Jung Woo Park, Chul Ho Jun

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

Highly efficient O-silylation of alcohol with vinylsilane was developed using a catalyst system consisting of [(COE)2RhCl]2 and HCl. In this reaction, a key intermediate is chlorosilane, generated from vinylsilane and HCl, which can be regenerated in the catalytic cycle. Various alcohols and vinylsilanes were applied to the preparation of silyl ether compounds with this catalyst system.

Original languageEnglish
Pages (from-to)4073-4076
Number of pages4
JournalOrganic Letters
Volume9
Issue number20
DOIs
Publication statusPublished - 2007 Sep 27

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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