Highly Efficient Pure-Blue Perovskite Light-Emitting Diode Leveraging CsPbBrxCl3−x/Cs4PbBrxCl6−x Nanocomposite Emissive Layer with Shallow Valence Band

In Young Choi, Sung Doo Baek, Ashkan Vakilipour Takaloo, Seung Yong Lee, Amir Hajibabaei, Kwang S. Kim, Jae Min Myoung

Research output: Contribution to journalArticlepeer-review

Abstract

Metal-halide perovskite light-emitting diodes (PeLEDs) have shown great advancement in green, red, and near-infrared regions with external quantum efficiencies (EQEs) exceeding 20%. However, blue PeLEDs, an essential part of displays and lightings, show limited progress compared to the other color counterparts. Herein, a highly efficient pure-blue PeLED is demonstrated by leveraging a novel CsPbBrxCl3-x/Cs4PbBrxCl6-x nanocomposite perovskite film as an emissive layer. The Cs4PbBrxCl6-x phase, the derived phase of CsPbBr3 perovskite with a mixed halide system, effectively passivates defects in CsPbBrxCl3-x, leading to high luminescence efficiency due to the significant reduction of nonradiative recombination. Furthermore, experimental and computational results confirmed that the compositionally optimized nanocomposite layer possesses a shallower valence band maximum (≈5.5 eV) than the pristine perovskite layer (≈5.9 eV), which is very advantageous in hole injection for device operation. The combined effects of the CsPbBrxCl3-x/Cs4PbBrxCl6-x nanocomposite render the fabricated blue PeLED to exhibit a pure-blue emission at 470 nm with a maximum EQE of 5.3%.

Original languageEnglish
Article number2102502
JournalAdvanced Optical Materials
Volume10
Issue number6
DOIs
Publication statusPublished - 2022 Mar 18

Bibliographical note

Funding Information:
I.Y.C., S.‐D.B., and A.V.T. contributed equally to this work. This work was supported by Samsung Research Funding & Incubation Center of Samsung Electronics under Project No. SRFC‐MA1901‐01. S.‐D.B. was supported by the Korea Initiative for fostering University of Research and Innovation (KIURI) Program of the National Research Foundation (NRF), funded by the Korean government (MSIT) (No. NRF‐2020M3H1A1077207).

Publisher Copyright:
© 2022 Wiley-VCH GmbH

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Atomic and Molecular Physics, and Optics

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