Highly enantioselective radical addition to N-benzoyl hydrazones using chiral ammonium salts

Ok Jang Doo; Yoon Kim Sang

doi:10.1021/ja807685r

Highly enantioselective radical addition to N-benzoyl hydrazones using chiral ammonium salts

Ok Jang Doo, Yoon Kim Sang

Chemistry and Medical Chemistry

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

In the presence of a protonated cinchonine derivative, radical addition reactions proceeded efficiently, affording addition adducts in high yields with an extremely high enantioselectivity. The chiral ammonium salt was recyclable after a simple aqueous workup. The reaction provides environmentally benign reaction conditions.

Original language	English
Pages (from-to)	16152-16153
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	130
Issue number	48
DOIs	https://doi.org/10.1021/ja807685r
Publication status	Published - 2008 Dec 3

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja807685r

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title = "Highly enantioselective radical addition to N-benzoyl hydrazones using chiral ammonium salts",

abstract = "In the presence of a protonated cinchonine derivative, radical addition reactions proceeded efficiently, affording addition adducts in high yields with an extremely high enantioselectivity. The chiral ammonium salt was recyclable after a simple aqueous workup. The reaction provides environmentally benign reaction conditions.",

author = "Doo, {Ok Jang} and Sang, {Yoon Kim}",

year = "2008",

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N2 - In the presence of a protonated cinchonine derivative, radical addition reactions proceeded efficiently, affording addition adducts in high yields with an extremely high enantioselectivity. The chiral ammonium salt was recyclable after a simple aqueous workup. The reaction provides environmentally benign reaction conditions.

AB - In the presence of a protonated cinchonine derivative, radical addition reactions proceeded efficiently, affording addition adducts in high yields with an extremely high enantioselectivity. The chiral ammonium salt was recyclable after a simple aqueous workup. The reaction provides environmentally benign reaction conditions.

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