Highly enantioselective radical addition to N-benzoyl hydrazones using chiral ammonium salts

Ok Jang Doo, Yoon Kim Sang

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

In the presence of a protonated cinchonine derivative, radical addition reactions proceeded efficiently, affording addition adducts in high yields with an extremely high enantioselectivity. The chiral ammonium salt was recyclable after a simple aqueous workup. The reaction provides environmentally benign reaction conditions.

Original languageEnglish
Pages (from-to)16152-16153
Number of pages2
JournalJournal of the American Chemical Society
Volume130
Issue number48
DOIs
Publication statusPublished - 2008 Dec 3

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Hydrazones
Addition reactions
Enantioselectivity
Ammonium Compounds
Salts
Derivatives
cinchonine

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

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abstract = "In the presence of a protonated cinchonine derivative, radical addition reactions proceeded efficiently, affording addition adducts in high yields with an extremely high enantioselectivity. The chiral ammonium salt was recyclable after a simple aqueous workup. The reaction provides environmentally benign reaction conditions.",
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Highly enantioselective radical addition to N-benzoyl hydrazones using chiral ammonium salts. / Doo, Ok Jang; Sang, Yoon Kim.

In: Journal of the American Chemical Society, Vol. 130, No. 48, 03.12.2008, p. 16152-16153.

Research output: Contribution to journalArticle

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AB - In the presence of a protonated cinchonine derivative, radical addition reactions proceeded efficiently, affording addition adducts in high yields with an extremely high enantioselectivity. The chiral ammonium salt was recyclable after a simple aqueous workup. The reaction provides environmentally benign reaction conditions.

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