Highly Hydrophobic ZIF-8/Carbon Nitride Foam with Hierarchical Porosity for Oil Capture and Chemical Fixation of CO2

Daeok Kim, Daewoo Kim, Onur Buyukcakir, Min Kyeong Kim, Kyriaki Polychronopoulou, Ali Coskun

Research output: Contribution to journalArticle

38 Citations (Scopus)

Abstract

The introduction of hierarchical porosity into metal-organic frameworks (MOFs) has been of considerable interest in gas separation and heterogeneous catalysis due to the efficient mass transfer kinetics through meso/macropores. Here, a facile, scalable approach is reported for the preparation of carbon nitride (CN) foams as structural templates with micrometer-sized pores and high nitrogen content of 25.6 wt% by the fast carbonization of low-cost melamine foam. The nitrogen functionalities of CN foam facilitate chemical anchoring and growth of ZIF-8 (zeolitic imidazolate frameworks) crystals, which leads to the development of hierarchical porosity. The growth of ZIF-8 crystals also renders CN foam, which is hydrophilic in nature, highly hydrophobic exhibiting 135° of water contact angle due to the enhanced surface roughness, thus creating a natural shield for the MOF crystals against water. The introduction of ZIF-8 crystals onto the CN foam enables selective absorption of oils up to 58 wt% from water/oil mixtures and also facilitates the highly efficient conversion of CO2 to chloropropene carbonate in a quantitative yield with excellent product selectivity. Importantly, this present approach could be extended to the vast number of MOF structures, including the ones suffering from water instability, for the preparation of highly functional materials for various applications.

Original languageEnglish
Article number1700706
JournalAdvanced Functional Materials
Volume27
Issue number23
DOIs
Publication statusPublished - 2017 Jun 20

Fingerprint

carbon nitrides
Carbon nitride
foams
Foams
Oils
Porosity
oils
porosity
Crystals
Water
Metals
water
crystals
Nitrogen
metals
nitrogen
melamine
preparation
Melamine
Functional materials

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Biomaterials
  • Condensed Matter Physics
  • Electrochemistry

Cite this

Kim, Daeok ; Kim, Daewoo ; Buyukcakir, Onur ; Kim, Min Kyeong ; Polychronopoulou, Kyriaki ; Coskun, Ali. / Highly Hydrophobic ZIF-8/Carbon Nitride Foam with Hierarchical Porosity for Oil Capture and Chemical Fixation of CO2 In: Advanced Functional Materials. 2017 ; Vol. 27, No. 23.
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Highly Hydrophobic ZIF-8/Carbon Nitride Foam with Hierarchical Porosity for Oil Capture and Chemical Fixation of CO2 . / Kim, Daeok; Kim, Daewoo; Buyukcakir, Onur; Kim, Min Kyeong; Polychronopoulou, Kyriaki; Coskun, Ali.

In: Advanced Functional Materials, Vol. 27, No. 23, 1700706, 20.06.2017.

Research output: Contribution to journalArticle

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