Highly selective catalytic Friedel-Crafts acylation and sulfonylation of activated aromatic compounds using indium metal

Doo Ok Jang; Kyung Soo Moon; Dae Hyan Cho; Joong Gon Kim

doi:10.1016/j.tetlet.2006.06.099

Highly selective catalytic Friedel-Crafts acylation and sulfonylation of activated aromatic compounds using indium metal

Doo Ok Jang, Kyung Soo Moon, Dae Hyan Cho, Joong Gon Kim

Chemistry and Medical Chemistry

Research output: Contribution to journal › Article

50 Citations (Scopus)

Abstract

The Friedel-Crafts acylation of activated benzenes with various aromatic and aliphatic acid chlorides was studied in the presence of indium metal. The reaction was accomplished in high isolated yields under solvent or solvent-less conditions. The method is also applicable for preparing diaryl sulfones from aromatic compounds and aryl sulfonyl chlorides.

Original language	English
Pages (from-to)	6063-6066
Number of pages	4
Journal	Tetrahedron Letters
Volume	47
Issue number	34
DOIs	https://doi.org/10.1016/j.tetlet.2006.06.099
Publication status	Published - 2006 Aug 21

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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Jang, D. O., Moon, K. S., Cho, D. H., & Kim, J. G. (2006). Highly selective catalytic Friedel-Crafts acylation and sulfonylation of activated aromatic compounds using indium metal. Tetrahedron Letters, 47(34), 6063-6066. https://doi.org/10.1016/j.tetlet.2006.06.099

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