Highly selective facilitated transport membranes for isoprene/n-pentane separation

Hyun Woo Choi; Dong Bum Kim; Dae Ki Choi; Byeong Sung Ahn; Hong gon Kim; Hoon Sik Kim; Chang Ha Lee; Joon Yong Sung

doi:10.1016/j.memsci.2005.12.029

Highly selective facilitated transport membranes for isoprene/n-pentane separation

Hyun Woo Choi, Dong Bum Kim, Dae Ki Choi, Byeong Sung Ahn, Hong gon Kim, Hoon Sik Kim, Chang Ha Lee, Joon Yong Sung

Department of Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The composite membranes containing sulfonated poly(ether ether)ketone (SPEEK)-AgNO₃ layers on top of polyester supports were prepared and tested for the separation of isoprene/n-pentane mixtures. The SPEEK-AgNO₃ membranes showed good selectivity for isoprene over n-pentane and long-term stability. The performances of the SPEEK-AgNO₃ membranes were significantly affected by the degree of sulfonation (DS) of SPEEK. The selectivity for isoprene over n-pentane increased with increasing DS of SPEEK. The separation of isoprene from n-pentane mixtures was also carried out using hollow fiber membranes containing SPEEK layers on top of PAN supports in a liquid-liquid membrane contactor system. The SPEEK-coated hollow fiber membranes was also effective the separation of real C₅ mixture consisting of about 20 different components.

Original language	English
Pages (from-to)	403-409
Number of pages	7
Journal	Journal of Membrane Science
Volume	279
Issue number	1-2
DOIs	https://doi.org/10.1016/j.memsci.2005.12.029
Publication status	Published - 2006 Aug 1

Bibliographical note

Funding Information:
This research was supported by a grant (BC1-108) from Carbon Dioxide Reduction and Sequestration Research Center, one of the 21st Century Frontier Programs funded by the Ministry of Science and Technology of the Korea government.

All Science Journal Classification (ASJC) codes

Biochemistry
Materials Science(all)
Physical and Theoretical Chemistry
Filtration and Separation

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10.1016/j.memsci.2005.12.029

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title = "Highly selective facilitated transport membranes for isoprene/n-pentane separation",

abstract = "The composite membranes containing sulfonated poly(ether ether)ketone (SPEEK)-AgNO3 layers on top of polyester supports were prepared and tested for the separation of isoprene/n-pentane mixtures. The SPEEK-AgNO3 membranes showed good selectivity for isoprene over n-pentane and long-term stability. The performances of the SPEEK-AgNO3 membranes were significantly affected by the degree of sulfonation (DS) of SPEEK. The selectivity for isoprene over n-pentane increased with increasing DS of SPEEK. The separation of isoprene from n-pentane mixtures was also carried out using hollow fiber membranes containing SPEEK layers on top of PAN supports in a liquid-liquid membrane contactor system. The SPEEK-coated hollow fiber membranes was also effective the separation of real C5 mixture consisting of about 20 different components.",

author = "Choi, {Hyun Woo} and Kim, {Dong Bum} and Choi, {Dae Ki} and Ahn, {Byeong Sung} and Kim, {Hong gon} and Kim, {Hoon Sik} and Lee, {Chang Ha} and Sung, {Joon Yong}",

note = "Funding Information: This research was supported by a grant (BC1-108) from Carbon Dioxide Reduction and Sequestration Research Center, one of the 21st Century Frontier Programs funded by the Ministry of Science and Technology of the Korea government. ",

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AU - Kim, Dong Bum

AU - Choi, Dae Ki

AU - Ahn, Byeong Sung

AU - Kim, Hong gon

AU - Kim, Hoon Sik

AU - Lee, Chang Ha

AU - Sung, Joon Yong

N1 - Funding Information: This research was supported by a grant (BC1-108) from Carbon Dioxide Reduction and Sequestration Research Center, one of the 21st Century Frontier Programs funded by the Ministry of Science and Technology of the Korea government.

PY - 2006/8/1

Y1 - 2006/8/1

N2 - The composite membranes containing sulfonated poly(ether ether)ketone (SPEEK)-AgNO3 layers on top of polyester supports were prepared and tested for the separation of isoprene/n-pentane mixtures. The SPEEK-AgNO3 membranes showed good selectivity for isoprene over n-pentane and long-term stability. The performances of the SPEEK-AgNO3 membranes were significantly affected by the degree of sulfonation (DS) of SPEEK. The selectivity for isoprene over n-pentane increased with increasing DS of SPEEK. The separation of isoprene from n-pentane mixtures was also carried out using hollow fiber membranes containing SPEEK layers on top of PAN supports in a liquid-liquid membrane contactor system. The SPEEK-coated hollow fiber membranes was also effective the separation of real C5 mixture consisting of about 20 different components.

AB - The composite membranes containing sulfonated poly(ether ether)ketone (SPEEK)-AgNO3 layers on top of polyester supports were prepared and tested for the separation of isoprene/n-pentane mixtures. The SPEEK-AgNO3 membranes showed good selectivity for isoprene over n-pentane and long-term stability. The performances of the SPEEK-AgNO3 membranes were significantly affected by the degree of sulfonation (DS) of SPEEK. The selectivity for isoprene over n-pentane increased with increasing DS of SPEEK. The separation of isoprene from n-pentane mixtures was also carried out using hollow fiber membranes containing SPEEK layers on top of PAN supports in a liquid-liquid membrane contactor system. The SPEEK-coated hollow fiber membranes was also effective the separation of real C5 mixture consisting of about 20 different components.

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Highly selective facilitated transport membranes for isoprene/n-pentane separation

Abstract

Bibliographical note

All Science Journal Classification (ASJC) codes

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