Holey 2D Nanosheets of Low-Valent Manganese Oxides with an Excellent Oxygen Catalytic Activity and a High Functionality as a Catalyst for Li–O2 Batteries

Kanyaporn Adpakpang, Seung Mi Oh, Daniel Adjei Agyeman, Xiaoyan Jin, Nutpaphat Jarulertwathana, In Young Kim, Thapanee Sarakonsri, Yong Mook Kang, Seong Ju Hwang

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

Holey 2D nanosheets of low-valent Mn2O3 can be synthesized by thermally induced phase transition of exfoliated layered MnO2 nanosheets. The heat treatment of layered MnO2 nanosheets at elevated temperatures leads not only to transitions to low-valent manganese oxides but also to the creation of surface hole in the 2D nanosheet crystallites. Despite distinct phase transitions, highly anisotropic 2D morphology of the precursor MnO2 material remains intact upon the heat treatment whereas the diameter of surface hole becomes larger with increasing heating temperature. The obtained holey 2D Mn2O3 nanosheets show promising electrocatalyst performances for oxygen evolution reaction, which are much superior to that of nonporous Mn2O3 crystal. Among the present materials, the holey Mn2O3 nanosheet calcined at 500 °C displays the best electrocatalyst functionality with markedly decreased overpotential, indicating the importance of heating condition in optimizing the electrocatalytic activity. Of prime importance is that this material shows much better catalytic activity for Li–O2 batteries than does nonporous Mn2O3, underscoring the critical role of porous 2D morphology in this functionality. This study clearly demonstrates the unique advantage of holey 2D nanosheet morphology in exploring economically feasible transition metal oxide-based electrocatalysts and electrodes for Li–O2 batteries.

Original languageEnglish
Article number1707106
JournalAdvanced Functional Materials
Volume28
Issue number17
DOIs
Publication statusPublished - 2018 Apr 25

Fingerprint

Manganese oxide
manganese oxides
electrocatalysts
Nanosheets
electric batteries
catalytic activity
Catalyst activity
Oxygen
catalysts
Catalysts
oxygen
heat treatment
Electrocatalysts
heating
crystallites
metal oxides
transition metals
Phase transitions
Heat treatment
temperature

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Biomaterials
  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Electrochemistry

Cite this

Adpakpang, Kanyaporn ; Oh, Seung Mi ; Agyeman, Daniel Adjei ; Jin, Xiaoyan ; Jarulertwathana, Nutpaphat ; Kim, In Young ; Sarakonsri, Thapanee ; Kang, Yong Mook ; Hwang, Seong Ju. / Holey 2D Nanosheets of Low-Valent Manganese Oxides with an Excellent Oxygen Catalytic Activity and a High Functionality as a Catalyst for Li–O2 Batteries. In: Advanced Functional Materials. 2018 ; Vol. 28, No. 17.
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abstract = "Holey 2D nanosheets of low-valent Mn2O3 can be synthesized by thermally induced phase transition of exfoliated layered MnO2 nanosheets. The heat treatment of layered MnO2 nanosheets at elevated temperatures leads not only to transitions to low-valent manganese oxides but also to the creation of surface hole in the 2D nanosheet crystallites. Despite distinct phase transitions, highly anisotropic 2D morphology of the precursor MnO2 material remains intact upon the heat treatment whereas the diameter of surface hole becomes larger with increasing heating temperature. The obtained holey 2D Mn2O3 nanosheets show promising electrocatalyst performances for oxygen evolution reaction, which are much superior to that of nonporous Mn2O3 crystal. Among the present materials, the holey Mn2O3 nanosheet calcined at 500 °C displays the best electrocatalyst functionality with markedly decreased overpotential, indicating the importance of heating condition in optimizing the electrocatalytic activity. Of prime importance is that this material shows much better catalytic activity for Li–O2 batteries than does nonporous Mn2O3, underscoring the critical role of porous 2D morphology in this functionality. This study clearly demonstrates the unique advantage of holey 2D nanosheet morphology in exploring economically feasible transition metal oxide-based electrocatalysts and electrodes for Li–O2 batteries.",
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Holey 2D Nanosheets of Low-Valent Manganese Oxides with an Excellent Oxygen Catalytic Activity and a High Functionality as a Catalyst for Li–O2 Batteries. / Adpakpang, Kanyaporn; Oh, Seung Mi; Agyeman, Daniel Adjei; Jin, Xiaoyan; Jarulertwathana, Nutpaphat; Kim, In Young; Sarakonsri, Thapanee; Kang, Yong Mook; Hwang, Seong Ju.

In: Advanced Functional Materials, Vol. 28, No. 17, 1707106, 25.04.2018.

Research output: Contribution to journalArticle

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AU - Adpakpang, Kanyaporn

AU - Oh, Seung Mi

AU - Agyeman, Daniel Adjei

AU - Jin, Xiaoyan

AU - Jarulertwathana, Nutpaphat

AU - Kim, In Young

AU - Sarakonsri, Thapanee

AU - Kang, Yong Mook

AU - Hwang, Seong Ju

PY - 2018/4/25

Y1 - 2018/4/25

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AB - Holey 2D nanosheets of low-valent Mn2O3 can be synthesized by thermally induced phase transition of exfoliated layered MnO2 nanosheets. The heat treatment of layered MnO2 nanosheets at elevated temperatures leads not only to transitions to low-valent manganese oxides but also to the creation of surface hole in the 2D nanosheet crystallites. Despite distinct phase transitions, highly anisotropic 2D morphology of the precursor MnO2 material remains intact upon the heat treatment whereas the diameter of surface hole becomes larger with increasing heating temperature. The obtained holey 2D Mn2O3 nanosheets show promising electrocatalyst performances for oxygen evolution reaction, which are much superior to that of nonporous Mn2O3 crystal. Among the present materials, the holey Mn2O3 nanosheet calcined at 500 °C displays the best electrocatalyst functionality with markedly decreased overpotential, indicating the importance of heating condition in optimizing the electrocatalytic activity. Of prime importance is that this material shows much better catalytic activity for Li–O2 batteries than does nonporous Mn2O3, underscoring the critical role of porous 2D morphology in this functionality. This study clearly demonstrates the unique advantage of holey 2D nanosheet morphology in exploring economically feasible transition metal oxide-based electrocatalysts and electrodes for Li–O2 batteries.

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