Hybrid gold nanoparticle-reduced graphene oxide nanosheets as active catalysts for highly efficient reduction of nitroarenes

Yuri Choi, Hee Son Bae, Eunyong Seo, Seonwan Jang, Kang Hyun Park, Byeong Su Kim

Research output: Contribution to journalArticle

178 Citations (Scopus)

Abstract

We demonstrate a simple, one-step synthesis of hybrid gold nanoparticle-graphene oxide nanosheets (Au-GO) through electrostatic self-assembly. This method affords a facile means of controlling the effective concentration of the active Au nanoparticles on the graphene sheets, but also offers the necessary stability of the resulting Au-GO nanostructure for catalytic transformation. Furthermore, this hybrid Au-GO is successfully employed in the catalytic reduction of a series of nitroarenes with high catalytic activity. Through careful investigation of the catalyst, we find the synergistic catalytic effect of Au nanoparticles and GO, further highlighting the significance of hybrid Au-GO nanostructure. Considering the wide potential applications of a two-dimensional graphene sheet as a host material for a variety of nanoparticles, the approach developed here may lead to new possibilities for the fabrication of hybrid nanoparticle-graphene nanosheet structures endowed with multiple functionalities.

Original languageEnglish
Pages (from-to)15431-15436
Number of pages6
JournalJournal of Materials Chemistry
Volume21
Issue number39
DOIs
Publication statusPublished - 2011 Oct 21

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Nanosheets
Gold
Oxides
Graphene
Nanoparticles
Catalysts
Nanostructures
Self assembly
Electrostatics
Catalyst activity
Fabrication

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Chemistry

Cite this

Choi, Yuri ; Bae, Hee Son ; Seo, Eunyong ; Jang, Seonwan ; Park, Kang Hyun ; Kim, Byeong Su. / Hybrid gold nanoparticle-reduced graphene oxide nanosheets as active catalysts for highly efficient reduction of nitroarenes. In: Journal of Materials Chemistry. 2011 ; Vol. 21, No. 39. pp. 15431-15436.
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Hybrid gold nanoparticle-reduced graphene oxide nanosheets as active catalysts for highly efficient reduction of nitroarenes. / Choi, Yuri; Bae, Hee Son; Seo, Eunyong; Jang, Seonwan; Park, Kang Hyun; Kim, Byeong Su.

In: Journal of Materials Chemistry, Vol. 21, No. 39, 21.10.2011, p. 15431-15436.

Research output: Contribution to journalArticle

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