Hybrid templated synthesis of crack-free, organized mesoporous TiO 2 electrodes for high efficiency solid-state dye-sensitized solar cells

Jung Tae Park, Won Seok Chi, Dong Kyu Roh, Sung Hoon Ahn, Jong Hak Kim

Research output: Contribution to journalArticle

37 Citations (Scopus)

Abstract

Organic/inorganic hybrid templates, i.e., aluminium oxide (Al 2O3) nanoparticles grafted with poly(oxyethylene) methacrylate, Al2O3-POEM, are synthesized via surface-initiated atom transfer radical polymerization (ATRP), as confirmed by Fourier transform-infrared spectroscopy (FT-IR) and thermogravimetric analysis (TGA). Upon combining the Al2O3-POEM with titanium(IV) isopropoxide (TTIP), hydrophilic TTIP is selectively confined in the hydrophilic POEM chains through hydrogen bonding interactions. Following the calcination at 450 °C and the selective etching of Al2O3 with NaOH, the OM-TiO2 films with high surface areas, good interconnectivity, and anatase phase are obtained. The solid-state dye-sensitized solar cells (ssDSSCs) fabricated with OM-TiO2 photoelectrodes and a polymerized ionic liquid (PIL) show a high energy conversion efficiency of 7.3% at 100 mW cm-2, which is one of the highest values for ssDSSCs. The high cell performance is due to the well-organized structure, resulting in improved dye loading, excellent pore filling of electrolyte, enhanced light harvesting, and reduced charge recombination.

Original languageEnglish
Pages (from-to)26-33
Number of pages8
JournalAdvanced Functional Materials
Volume23
Issue number1
DOIs
Publication statusPublished - 2013 Jan 7

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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