Hydrogenation of Fluorographite and Fluorographene: An Easy Way to Produce Highly Hydrogenated Graphene

Daniel Bouša; Vlastimil Mazánek; David Sedmidubský; Ondřej Jankovský; Martin Pumera; Zdeněk Sofer

doi:10.1002/chem.201800236

Hydrogenation of Fluorographite and Fluorographene: An Easy Way to Produce Highly Hydrogenated Graphene

Daniel Bouša, Vlastimil Mazánek, David Sedmidubský, Ondřej Jankovský, Martin Pumera, Zdeněk Sofer

Department of Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Fluorographene is an excellent precursor for the synthesis of graphene derivatives. Relative to pure graphene, fluorographene possesses higher reactivity and, in comparison with graphene oxide, is also homogenous in composition, which enables the preparation of well-defined materials. Recently, it has been shown that several graphene derivatives can be synthesized from fluorographene, thus yielding various products such as graphene acid or alkylated graphene. This study focuses on the hydrogenation of fluorographene by using various hydrogenation reactions, including the use complex hydrides and solvated electrons in different media. In addition, a comparison of these reactions shows that fluorinated graphite has significantly lower reactivity than fluorographene. The conversion rates of these reactions are higher when fluorographene is used relative to fluorographite. These reactions can be used to tune the hydrogen/fluorine composition on a graphene backbone.

Original language	English
Pages (from-to)	8350-8360
Number of pages	11
Journal	Chemistry - A European Journal
Volume	24
Issue number	33
DOIs	https://doi.org/10.1002/chem.201800236
Publication status	Published - 2018 Jun 12

Bibliographical note

Funding Information:
The project was supported by Czech Science Foundation (GACR No. 16-05167S) and by Specific university research (MSMT no. 20-SVV/2018). This work was created with the financial support of the Neuron Foundation for science support. This work was supported by the project Advanced Functional Nanorobots (reg. No. CZ.02.1.01/0.0/0.0/15_003/0000444 financed by the EFRR).

Publisher Copyright:
© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

All Science Journal Classification (ASJC) codes

Catalysis
Organic Chemistry

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10.1002/chem.201800236

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abstract = "Fluorographene is an excellent precursor for the synthesis of graphene derivatives. Relative to pure graphene, fluorographene possesses higher reactivity and, in comparison with graphene oxide, is also homogenous in composition, which enables the preparation of well-defined materials. Recently, it has been shown that several graphene derivatives can be synthesized from fluorographene, thus yielding various products such as graphene acid or alkylated graphene. This study focuses on the hydrogenation of fluorographene by using various hydrogenation reactions, including the use complex hydrides and solvated electrons in different media. In addition, a comparison of these reactions shows that fluorinated graphite has significantly lower reactivity than fluorographene. The conversion rates of these reactions are higher when fluorographene is used relative to fluorographite. These reactions can be used to tune the hydrogen/fluorine composition on a graphene backbone.",

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Hydrogenation of Fluorographite and Fluorographene: An Easy Way to Produce Highly Hydrogenated Graphene

Abstract

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