Hydrotreating of petroleum vacuum residue in supercritical aromatic solvents with activated carbons

Tran Tan Viet, Jae Hyuk Lee, Il Yong Jeong, Jae Wook Ryu, Chang Ha Lee

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Petroleum vacuum residue (VR) isthe heaviest fraction of refine petroleum processes, which contains higherportions of asphaltene and higher concentration ofcontaminants such as sulfur, nitrogen, and heavy metals. Conversion of VR intolight fraction without heteroatoms becomes important more and more in the refinerybecause of the short supply of light sweet crude oil as well as the steep increaseof crude oil price. In the study, the hydrotreating of VR in supercritical hydrocarbon solvents was conducted with activated carbon (AC) as a catalyst in batch reactor. Two kinds ofsupercritical hydrocarbon solvents were applied: n-alkanes (n-hexane and n-dodecane) and aromatic solvents (toluene and m-xylene). Along with the conversion level andcoke formation of hydrotreating VR reaction, the distribution of oil product (naphtha, middle distillate, vacuum gas oil andresidue) in each supercritical hydrocarbon solvent was evaluated. The supercritical aromatic solvent gave much smaller naphtha fraction but higher middle distillate fraction than the supercritical n-alkanes did. It implies that the conversion level and product quality can be controlled by the selected supercritical solvent. In addition, the effect of hydrogen partial pressure and surface properties of AC on the hydrotreating VR reaction were also investigated.

Original languageEnglish
Title of host publication11AIChE - 2011 AIChE Annual Meeting, Conference Proceedings
Publication statusPublished - 2011 Dec 1
Event2011 AIChE Annual Meeting, 11AIChE - Minneapolis, MN, United States
Duration: 2011 Oct 162011 Oct 21

Publication series

Name11AIChE - 2011 AIChE Annual Meeting, Conference Proceedings

Other

Other2011 AIChE Annual Meeting, 11AIChE
CountryUnited States
CityMinneapolis, MN
Period11/10/1611/10/21

Fingerprint

Petroleum
Activated carbon
Crude oil
Vacuum
Hydrocarbons
Alkanes
Naphthas
Paraffins
Toluene
Batch reactors
Xylene
Gas oils
Heavy Metals
Hexane
Sulfur
Partial pressure
Heavy metals
Surface properties
Hydrogen
Oils

All Science Journal Classification (ASJC) codes

  • Chemical Engineering(all)

Cite this

Viet, T. T., Lee, J. H., Jeong, I. Y., Ryu, J. W., & Lee, C. H. (2011). Hydrotreating of petroleum vacuum residue in supercritical aromatic solvents with activated carbons. In 11AIChE - 2011 AIChE Annual Meeting, Conference Proceedings (11AIChE - 2011 AIChE Annual Meeting, Conference Proceedings).
Viet, Tran Tan ; Lee, Jae Hyuk ; Jeong, Il Yong ; Ryu, Jae Wook ; Lee, Chang Ha. / Hydrotreating of petroleum vacuum residue in supercritical aromatic solvents with activated carbons. 11AIChE - 2011 AIChE Annual Meeting, Conference Proceedings. 2011. (11AIChE - 2011 AIChE Annual Meeting, Conference Proceedings).
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abstract = "Petroleum vacuum residue (VR) isthe heaviest fraction of refine petroleum processes, which contains higherportions of asphaltene and higher concentration ofcontaminants such as sulfur, nitrogen, and heavy metals. Conversion of VR intolight fraction without heteroatoms becomes important more and more in the refinerybecause of the short supply of light sweet crude oil as well as the steep increaseof crude oil price. In the study, the hydrotreating of VR in supercritical hydrocarbon solvents was conducted with activated carbon (AC) as a catalyst in batch reactor. Two kinds ofsupercritical hydrocarbon solvents were applied: n-alkanes (n-hexane and n-dodecane) and aromatic solvents (toluene and m-xylene). Along with the conversion level andcoke formation of hydrotreating VR reaction, the distribution of oil product (naphtha, middle distillate, vacuum gas oil andresidue) in each supercritical hydrocarbon solvent was evaluated. The supercritical aromatic solvent gave much smaller naphtha fraction but higher middle distillate fraction than the supercritical n-alkanes did. It implies that the conversion level and product quality can be controlled by the selected supercritical solvent. In addition, the effect of hydrogen partial pressure and surface properties of AC on the hydrotreating VR reaction were also investigated.",
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Viet, TT, Lee, JH, Jeong, IY, Ryu, JW & Lee, CH 2011, Hydrotreating of petroleum vacuum residue in supercritical aromatic solvents with activated carbons. in 11AIChE - 2011 AIChE Annual Meeting, Conference Proceedings. 11AIChE - 2011 AIChE Annual Meeting, Conference Proceedings, 2011 AIChE Annual Meeting, 11AIChE, Minneapolis, MN, United States, 11/10/16.

Hydrotreating of petroleum vacuum residue in supercritical aromatic solvents with activated carbons. / Viet, Tran Tan; Lee, Jae Hyuk; Jeong, Il Yong; Ryu, Jae Wook; Lee, Chang Ha.

11AIChE - 2011 AIChE Annual Meeting, Conference Proceedings. 2011. (11AIChE - 2011 AIChE Annual Meeting, Conference Proceedings).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

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Viet TT, Lee JH, Jeong IY, Ryu JW, Lee CH. Hydrotreating of petroleum vacuum residue in supercritical aromatic solvents with activated carbons. In 11AIChE - 2011 AIChE Annual Meeting, Conference Proceedings. 2011. (11AIChE - 2011 AIChE Annual Meeting, Conference Proceedings).