Hydroxy-group directing hydroiminoacylation of α,ω-dien-3-ol with aidimine by Wilkinson's Complex

Jun Chul-Ho, Han Jong-Soo, Kang Jung-Bu, Kim Sun-Il

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

Ferrocenecarboxaldimine (1) reacted with 1,4-pentadien-3-ol (2) under Wilkinson's catalyst (3) to give the hydroacylated product 6 after hydrolysis of the resulting ketimine 4. Prolonged reaction time induced the isomerization of 6 to 7. When 1,5-hexadien-3-ol (11) was used, the hydroiminoacylation of the allyl alcohol group gave predominantly 12, which showed a remarkable hydroxy-group directing effect.

Original languageEnglish
Pages (from-to)183-189
Number of pages7
JournalJournal of Organometallic Chemistry
Volume474
Issue number1-2
DOIs
Publication statusPublished - 1994 Jul 12

Fingerprint

Isomerization
Hydrolysis
Alcohols
Catalysts
reaction time
isomerization
hydrolysis
alcohols
catalysts
products
ketimine
allyl alcohol

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

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abstract = "Ferrocenecarboxaldimine (1) reacted with 1,4-pentadien-3-ol (2) under Wilkinson's catalyst (3) to give the hydroacylated product 6 after hydrolysis of the resulting ketimine 4. Prolonged reaction time induced the isomerization of 6 to 7. When 1,5-hexadien-3-ol (11) was used, the hydroiminoacylation of the allyl alcohol group gave predominantly 12, which showed a remarkable hydroxy-group directing effect.",
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Hydroxy-group directing hydroiminoacylation of α,ω-dien-3-ol with aidimine by Wilkinson's Complex. / Chul-Ho, Jun; Jong-Soo, Han; Jung-Bu, Kang; Sun-Il, Kim.

In: Journal of Organometallic Chemistry, Vol. 474, No. 1-2, 12.07.1994, p. 183-189.

Research output: Contribution to journalArticle

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AU - Sun-Il, Kim

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AB - Ferrocenecarboxaldimine (1) reacted with 1,4-pentadien-3-ol (2) under Wilkinson's catalyst (3) to give the hydroacylated product 6 after hydrolysis of the resulting ketimine 4. Prolonged reaction time induced the isomerization of 6 to 7. When 1,5-hexadien-3-ol (11) was used, the hydroiminoacylation of the allyl alcohol group gave predominantly 12, which showed a remarkable hydroxy-group directing effect.

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