Hydroxy-group directing hydroiminoacylation of α,ω-dien-3-ol with aidimine by Wilkinson's Complex

Jun Chul-Ho; Han Jong-Soo; Kang Jung-Bu; Kim Sun-Il

doi:10.1016/0022-328X(94)84064-4

Hydroxy-group directing hydroiminoacylation of α,ω-dien-3-ol with aidimine by Wilkinson's Complex

Jun Chul-Ho, Han Jong-Soo, Kang Jung-Bu, Kim Sun-Il

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

Ferrocenecarboxaldimine (1) reacted with 1,4-pentadien-3-ol (2) under Wilkinson's catalyst (3) to give the hydroacylated product 6 after hydrolysis of the resulting ketimine 4. Prolonged reaction time induced the isomerization of 6 to 7. When 1,5-hexadien-3-ol (11) was used, the hydroiminoacylation of the allyl alcohol group gave predominantly 12, which showed a remarkable hydroxy-group directing effect.

Original language	English
Pages (from-to)	183-189
Number of pages	7
Journal	Journal of Organometallic Chemistry
Volume	474
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(94)84064-4
Publication status	Published - 1994 Jul 12

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/0022-328X(94)84064-4

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title = "Hydroxy-group directing hydroiminoacylation of α,ω-dien-3-ol with aidimine by Wilkinson's Complex",

abstract = "Ferrocenecarboxaldimine (1) reacted with 1,4-pentadien-3-ol (2) under Wilkinson's catalyst (3) to give the hydroacylated product 6 after hydrolysis of the resulting ketimine 4. Prolonged reaction time induced the isomerization of 6 to 7. When 1,5-hexadien-3-ol (11) was used, the hydroiminoacylation of the allyl alcohol group gave predominantly 12, which showed a remarkable hydroxy-group directing effect.",

author = "Jun Chul-Ho and Han Jong-Soo and Kang Jung-Bu and Kim Sun-Il",

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AU - Chul-Ho, Jun

AU - Jong-Soo, Han

AU - Jung-Bu, Kang

AU - Sun-Il, Kim

PY - 1994/7/12

Y1 - 1994/7/12

N2 - Ferrocenecarboxaldimine (1) reacted with 1,4-pentadien-3-ol (2) under Wilkinson's catalyst (3) to give the hydroacylated product 6 after hydrolysis of the resulting ketimine 4. Prolonged reaction time induced the isomerization of 6 to 7. When 1,5-hexadien-3-ol (11) was used, the hydroiminoacylation of the allyl alcohol group gave predominantly 12, which showed a remarkable hydroxy-group directing effect.

AB - Ferrocenecarboxaldimine (1) reacted with 1,4-pentadien-3-ol (2) under Wilkinson's catalyst (3) to give the hydroacylated product 6 after hydrolysis of the resulting ketimine 4. Prolonged reaction time induced the isomerization of 6 to 7. When 1,5-hexadien-3-ol (11) was used, the hydroiminoacylation of the allyl alcohol group gave predominantly 12, which showed a remarkable hydroxy-group directing effect.

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ER -

Hydroxy-group directing hydroiminoacylation of α,ω-dien-3-ol with aidimine by Wilkinson's Complex

Abstract

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