Identification of Killer Defects in Kesterite Thin-Film Solar Cells

Sunghyun Kim, Ji Sang Park, Aron Walsh

Research output: Contribution to journalArticle

20 Citations (Scopus)

Abstract

Nonradiative electron-hole recombination is the bottleneck to efficient kesterite thin-film solar cells. We have performed a search for active point defect recombination centers using first-principles calculations. We show that the anion vacancy in Cu2ZnSnS4 (CZTS) is electrically benign without a donor level in the band gap. VS can still act as an efficient nonradiative site through the aid of an intermediate excited state involving electron capture by Sn. The bipolaron associated with Sn4+ to Sn2+ two-electron reduction stabilizes the neutral sulfur vacancy over the charged states; however, we demonstrate a mechanism whereby nonradiative recombination can occur via multiphonon emission. Our study highlights that defect-mediated recombination does not require a charge transition level deep in the band gap of a semiconductor. We further identify SnZn as the origin of persistent electron trapping/detrapping in kesterite photovoltaic devices, which is suppressed in the selenide compound.

Original languageEnglish
Pages (from-to)496-500
Number of pages5
JournalACS Energy Letters
Volume3
Issue number2
DOIs
Publication statusPublished - 2018 Feb 9

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Defects
Electrons
Vacancies
Energy gap
Point defects
Electron transitions
Sulfur
Excited states
Anions
Negative ions
Semiconductor materials
Thin film solar cells
Cu2ZnSnS4

All Science Journal Classification (ASJC) codes

  • Chemistry (miscellaneous)
  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Energy Engineering and Power Technology
  • Materials Chemistry

Cite this

Kim, Sunghyun ; Park, Ji Sang ; Walsh, Aron. / Identification of Killer Defects in Kesterite Thin-Film Solar Cells. In: ACS Energy Letters. 2018 ; Vol. 3, No. 2. pp. 496-500.
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Identification of Killer Defects in Kesterite Thin-Film Solar Cells. / Kim, Sunghyun; Park, Ji Sang; Walsh, Aron.

In: ACS Energy Letters, Vol. 3, No. 2, 09.02.2018, p. 496-500.

Research output: Contribution to journalArticle

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