Impregnation approach for poly(vinylidene fluoride)/tin oxide nanotube composites with high tribological performance

Min Su Park; Jin Kyu Kim; Tong Seok Han; Jung Tae Park; Jong Hak Kim

doi:10.1016/j.jmst.2019.07.038

Impregnation approach for poly(vinylidene fluoride)/tin oxide nanotube composites with high tribological performance

Min Su Park, Jin Kyu Kim, Tong Seok Han, Jung Tae Park, Jong Hak Kim

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

We report a composite material with the high tribological performance, which consists of one-dimensional SnO₂ nanotubes (ST) and a high molecular weight poly(vinylidene fluoride) (PVDF) matrix in terms of nano-impregnation. Dissolution of PVDF in N,N-dimethylformamide (DMF) resulted in a facile penetration of PVDF into the inner hollow voids of ST, leading to the close contact. Interaction between PVDF and ST results in a beneficial effect on the chain arrangement of PVDF, providing an α-phase with better tribological property. Upon ST incorporation, the friction coefficient decreased by 85.0% to 0.408, and the specific wear rate decreased by 69.1% to 0.412, demonstrating the pivotal role of ST as a self-lubricating material due to a large interactive area and PVDF chain rearrangement.

Original language	English
Pages (from-to)	19-25
Number of pages	7
Journal	Journal of Materials Science and Technology
Volume	37
DOIs	https://doi.org/10.1016/j.jmst.2019.07.038
Publication status	Published - 2020 Jan 15

Bibliographical note

Funding Information:
This work was supported financially by a grant from the National Research Foundation (NRF) of South Korea, funded by the Ministry of Science, ICT and Future Planning (Nos. NRF-2017R1A4A1014569 and NRF-2018M3A7B4071535).

Funding Information:
This work was supported financially by a grant from the National Research Foundation (NRF) of South Korea , funded by the Ministry of Science, ICT and Future Planning (Nos. NRF-2017R1A4A1014569 and NRF-2018M3A7B4071535 ). Appendix A

Publisher Copyright:
© 2019

All Science Journal Classification (ASJC) codes

Ceramics and Composites
Mechanics of Materials
Mechanical Engineering
Polymers and Plastics
Metals and Alloys
Materials Chemistry

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10.1016/j.jmst.2019.07.038

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title = "Impregnation approach for poly(vinylidene fluoride)/tin oxide nanotube composites with high tribological performance",

abstract = "We report a composite material with the high tribological performance, which consists of one-dimensional SnO2 nanotubes (ST) and a high molecular weight poly(vinylidene fluoride) (PVDF) matrix in terms of nano-impregnation. Dissolution of PVDF in N,N-dimethylformamide (DMF) resulted in a facile penetration of PVDF into the inner hollow voids of ST, leading to the close contact. Interaction between PVDF and ST results in a beneficial effect on the chain arrangement of PVDF, providing an α-phase with better tribological property. Upon ST incorporation, the friction coefficient decreased by 85.0% to 0.408, and the specific wear rate decreased by 69.1% to 0.412, demonstrating the pivotal role of ST as a self-lubricating material due to a large interactive area and PVDF chain rearrangement.",

author = "{Su Park}, Min and Kim, {Jin Kyu} and Han, {Tong Seok} and Park, {Jung Tae} and Kim, {Jong Hak}",

note = "Funding Information: This work was supported financially by a grant from the National Research Foundation (NRF) of South Korea, funded by the Ministry of Science, ICT and Future Planning (Nos. NRF-2017R1A4A1014569 and NRF-2018M3A7B4071535). Funding Information: This work was supported financially by a grant from the National Research Foundation (NRF) of South Korea , funded by the Ministry of Science, ICT and Future Planning (Nos. NRF-2017R1A4A1014569 and NRF-2018M3A7B4071535 ). Appendix A Publisher Copyright: {\textcopyright} 2019",

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doi = "10.1016/j.jmst.2019.07.038",

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AU - Su Park, Min

AU - Kim, Jin Kyu

AU - Han, Tong Seok

AU - Park, Jung Tae

AU - Kim, Jong Hak

N1 - Funding Information: This work was supported financially by a grant from the National Research Foundation (NRF) of South Korea, funded by the Ministry of Science, ICT and Future Planning (Nos. NRF-2017R1A4A1014569 and NRF-2018M3A7B4071535). Funding Information: This work was supported financially by a grant from the National Research Foundation (NRF) of South Korea , funded by the Ministry of Science, ICT and Future Planning (Nos. NRF-2017R1A4A1014569 and NRF-2018M3A7B4071535 ). Appendix A Publisher Copyright: © 2019

PY - 2020/1/15

Y1 - 2020/1/15

N2 - We report a composite material with the high tribological performance, which consists of one-dimensional SnO2 nanotubes (ST) and a high molecular weight poly(vinylidene fluoride) (PVDF) matrix in terms of nano-impregnation. Dissolution of PVDF in N,N-dimethylformamide (DMF) resulted in a facile penetration of PVDF into the inner hollow voids of ST, leading to the close contact. Interaction between PVDF and ST results in a beneficial effect on the chain arrangement of PVDF, providing an α-phase with better tribological property. Upon ST incorporation, the friction coefficient decreased by 85.0% to 0.408, and the specific wear rate decreased by 69.1% to 0.412, demonstrating the pivotal role of ST as a self-lubricating material due to a large interactive area and PVDF chain rearrangement.

AB - We report a composite material with the high tribological performance, which consists of one-dimensional SnO2 nanotubes (ST) and a high molecular weight poly(vinylidene fluoride) (PVDF) matrix in terms of nano-impregnation. Dissolution of PVDF in N,N-dimethylformamide (DMF) resulted in a facile penetration of PVDF into the inner hollow voids of ST, leading to the close contact. Interaction between PVDF and ST results in a beneficial effect on the chain arrangement of PVDF, providing an α-phase with better tribological property. Upon ST incorporation, the friction coefficient decreased by 85.0% to 0.408, and the specific wear rate decreased by 69.1% to 0.412, demonstrating the pivotal role of ST as a self-lubricating material due to a large interactive area and PVDF chain rearrangement.

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Impregnation approach for poly(vinylidene fluoride)/tin oxide nanotube composites with high tribological performance

Abstract

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