Improved dielectric properties of BeO thin films grown by plasma enhanced atomic layer deposition

Yoonseo Jang, Seung Min Lee, Do Hwan Jung, Jung Hwan Yum, Eric S. Larsen, Christopher W. Bielawski, Jungwoo Oh

Research output: Contribution to journalArticlepeer-review

Abstract

Beryllium oxide (BeO) thin films were grown on a p-type Si substrate by plasma enhanced atomic layer deposition (PEALD) using diethylberyllium as a precursor and O2 plasma. The PEALD BeO exhibited self-saturation and linear growth rates. The dielectric properties of PEALD were compared with those of thermal atomic layer deposition (ThALD). X-ray photoelectron spectroscopy was performed to determine the bandgap energy of PEALD BeO (8.0 eV) and ThALD BeO (7.9 eV). Capacitance–voltage curves revealed that PEALD BeO had low hysteresis and frequency dispersion compared to ThALD BeO. In addition, PEALD showed a dielectric constant of 7.15 (at 1 MHz) and low leakage current (7.25×10-9 A/cm2 at −1 MV/cm). These results indicate that the highly activated radicals from oxygen plasma prompt the chemical reaction at the substrate, thus reducing nucleation delay and interface trap density.

Original languageEnglish
Article number107661
JournalSolid-State Electronics
Volume163
DOIs
Publication statusPublished - 2020 Jan

Bibliographical note

Funding Information:
This research was supported by Korea Electric Power Corporation (Grant number 3): R18XA06-03 and by the Ministry of Science and ICT (MSIT), Korea, under the ICT Consilience Creative Program (IITP-2019-2017-0-01015), supervised by the Institute for Information & Communications Technology Promotion (IITP). CWB, JHY, and ESL are grateful to the Institute for Basic Science (IBS-R019) as well as the BK21 Plus Program funded by the Ministry of Education and the National Research Foundation of Korea for their support.

Funding Information:
This research was supported by Korea Electric Power Corporation (Grant number 3): R18XA06-03 and by the Ministry of Science and ICT ( MSIT ), Korea, under the ICT Consilience Creative Program ( IITP-2019-2017-0-01015 ), supervised by the Institute for Information & Communications Technology Promotion (IITP). CWB, JHY, and ESL are grateful to the Institute for Basic Science ( IBS-R019 ) as well as the BK21 Plus Program funded by the Ministry of Education and the National Research Foundation of Korea for their support.

Publisher Copyright:
© 2019 Elsevier Ltd

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Electrical and Electronic Engineering
  • Materials Chemistry

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