Improvement of Gas-Sensing Performance of Large-Area Tungsten Disulfide Nanosheets by Surface Functionalization

Kyung Yong Ko, Jeong Gyu Song, Youngjun Kim, Taejin Choi, Sera Shin, Chang Wan Lee, Kyounghoon Lee, Jahyun Koo, Hoonkyung Lee, Jongbaeg Kim, Taeyoon Lee, Jusang Park, Hyungjun Kim

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140 Citations (Scopus)

Abstract

Semiconducting two-dimensional (2D) transition metal dichalcogenides (TMDCs) are promising gas-sensing materials due to their large surface-to-volume ratio. However, their poor gas-sensing performance resulting from the low response, incomplete recovery, and insufficient selectivity hinders the realization of high-performance 2D TMDC gas sensors. Here, we demonstrate the improvement of gas-sensing performance of large-area tungsten disulfide (WS2) nanosheets through surface functionalization using Ag nanowires (NWs). Large-area WS2 nanosheets were synthesized through atomic layer deposition of WO3 followed by sulfurization. The pristine WS2 gas sensors exhibited a significant response to acetone and NO2 but an incomplete recovery in the case of NO2 sensing. After AgNW functionalization, the WS2 gas sensor showed dramatically improved response (667%) and recovery upon NO2 exposure. Our results establish that the proposed method is a promising strategy to improve 2D TMDC gas sensors.

Original languageEnglish
Pages (from-to)9287-9296
Number of pages10
JournalACS Nano
Volume10
Issue number10
DOIs
Publication statusPublished - 2016 Oct 25

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Engineering(all)
  • Physics and Astronomy(all)

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    Ko, K. Y., Song, J. G., Kim, Y., Choi, T., Shin, S., Lee, C. W., Lee, K., Koo, J., Lee, H., Kim, J., Lee, T., Park, J., & Kim, H. (2016). Improvement of Gas-Sensing Performance of Large-Area Tungsten Disulfide Nanosheets by Surface Functionalization. ACS Nano, 10(10), 9287-9296. https://doi.org/10.1021/acsnano.6b03631