Improvement of ZnO nanorod-based dye-sensitized solar cell efficiency by Al-doping

Sining Yun, Juneyoung Lee, Jooyoung Chung, Sangwoo Lim

Research output: Contribution to journalArticle

72 Citations (Scopus)

Abstract

The current study investigates the performance of dye-sensitized solar cells (DSSCs) based on Al-doped and undoped ZnO nanorod arrays synthesized by a simple hydrothermal method. Current densityvoltage (JV) characterizations indicate that Al-doping in ZnO crystal structure can significantly improve current densities and the energy conversion efficiency (η) of ZnO nanorod-based DSSCs. The maximum η, 1.34%, was achieved in DSSC when Al-doped ZnO nanorod arrays were grown in 0.04 M zinc acetate dihydrate solution with 5 mM aluminum nitrate nonahydrate. This result represents a large increase of η in Al-doped ZnO nanorod-based DSSCs as compared to undoped (0.05%). The improved DSSC photovoltaic performance can be attributed to two main factors: (1) increased light harvesting efficiency due to a large amount of N719 adsorbed on the large surface area of Al-doped ZnO nanorod arrays, and (2) increased electrical conductivity due to A13 ion doped into the ZnO lattice at the divalent Zn2 site, allowing electrons to move easily into the Al-doped ZnO conduction band.

Original languageEnglish
Pages (from-to)1724-1731
Number of pages8
JournalJournal of Physics and Chemistry of Solids
Volume71
Issue number12
DOIs
Publication statusPublished - 2010 Dec 1

Fingerprint

Nanorods
nanorods
solar cells
dyes
Doping (additives)
Zinc Acetate
energy conversion efficiency
Conduction bands
Energy conversion
Conversion efficiency
nitrates
acetates
Nitrates
conduction bands
Zinc
Current density
zinc
Crystal structure
Dye-sensitized solar cells
Ions

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Yun, Sining ; Lee, Juneyoung ; Chung, Jooyoung ; Lim, Sangwoo. / Improvement of ZnO nanorod-based dye-sensitized solar cell efficiency by Al-doping. In: Journal of Physics and Chemistry of Solids. 2010 ; Vol. 71, No. 12. pp. 1724-1731.
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Improvement of ZnO nanorod-based dye-sensitized solar cell efficiency by Al-doping. / Yun, Sining; Lee, Juneyoung; Chung, Jooyoung; Lim, Sangwoo.

In: Journal of Physics and Chemistry of Solids, Vol. 71, No. 12, 01.12.2010, p. 1724-1731.

Research output: Contribution to journalArticle

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