Incorporation of organic compound into silica matrix by a sol-gel process for NLO applications

Yong Gun Shul, Dong Jo Lee, Jae Suk Lee, Tatsuo Wada

Research output: Contribution to journalArticle

Abstract

In this work, MNA (2-methyl-4-nitroaniline) and substituted carbazoles were incorporated into silica matrix to form composite thin films on the glass substrate by a sol-gel processing for NLO applications. In the composite thin films, the thermal stability was dependent on the type of functional groups incorporated into the organic compounds. Carbazole-2 (5-intro-9-hydroxylethyl-carbazole) which has a terminal -OH group showed enhanced thermal stability, whereas carbazole-1 (5-nitro-9-ethyl-carbazole) and MNA, which do not have a reactive functional group, showed rapid degradation upon thermal treatment. This strongly suggests that the thermal stability of incorporated organic compounds can be enhanced by a reactive terminal group in organic compound without severely damaging the NLO property.

Original languageEnglish
Pages (from-to)72-73
Number of pages2
JournalJournal of the Ceramic Society of Japan. International ed.
Volume101
Issue number1
Publication statusPublished - 1993 Jan 1

All Science Journal Classification (ASJC) codes

  • Engineering(all)

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