Incorporation of organic compound into silica matrix by a sol-gel process for NLO applications

Yong Gun Shul, Dong Jo Lee, Jae Suk Lee, Tatsuo Wada

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

In this work, MNA (2-methyl-4-nitroaniline) and substituted carbazoles were incorporated into silica matrix to form composite thin films on the glass substrate by a sol-gel processing for NLO applications. In the composite thin films, the thermal stability was dependent on the type of functional groups incorporated into the organic compounds. Carbazole-2(5-nitro-9-hydroxylethyl-carbazole) which has a terminal -OH group showed enhanced thermal stability, whereas carbazole-1 (5-nitro-9-ethyl-carbazole) and MNA, which do not have a reactive functional group, showed rapid degradation upon thermal treatment. This strongly suggests that the thermal stability of incorporated organic compounds can be enhanced by a reactive terminal group in organic compound without severely damaging the NLO property.

Original languageEnglish
Pages (from-to)76-77
Number of pages2
JournalNippon Seramikkusu Kyokai Gakujutsu Ronbunshi/Journal of the Ceramic Society of Japan
Volume101
Issue number1169
DOIs
Publication statusPublished - 1993

All Science Journal Classification (ASJC) codes

  • Ceramics and Composites
  • Chemistry(all)
  • Condensed Matter Physics
  • Materials Chemistry

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