Indium Phosphide Quantum Dots Integrated with Cadmium Sulfide Nanorods for Photocatalytic Carbon Dioxide Reduction

Khai H. Do, D. Praveen Kumar, A. Putta Rangappa, Yul Hong, D. Amaranatha Reddy, Tae Kyu Kim

Research output: Contribution to journalArticlepeer-review

15 Citations (Scopus)


Photocatalytic conversion of CO2 into storable fuels is an attractive way to simultaneously address worldwide energy demands and environmental problems. Semiconductor quantum dots (QDs) have gained prominence as candidates for photocatalytic applications due to their many advantages, which include tunability for advanced electronic, optical, and surface properties. Indium phosphide (InP) quantum dots are semiconducting QDs with enormous potential for solar-driven CO2 reduction. Their advantages include a tunable bandgap, diverse surface chemistry, and nontoxicity. InP QDs and CdS nanorods were integrated using a simple and inexpensive method. CO2 photoreduction by the CdS-InP composites was evaluated in aqueous solution using triethanolamine as a sacrificial donor. The crystal structures, surface compositions, and morphologies were investigated via X-ray diffraction analysis, X-ray photoelectron spectroscopy, and transmission electron microscopy, respectively. The UV-visible diffuse reflectance spectra of the CdS-InP composites indicated efficient visible light utilization in the 500–550 nm range. The results of photoelectrochemical and photoluminescence analyses illustrated effective charge separation in the composites. The photocatalytic activity of the as-synthesized composites was superior to that of pure CdS. The CO evolution rate of the optimized composite was 216 μmol h−1 g−1 during the first three hours of irradiation and increased steadily over the next 62 hours. We also studied the influences of different solvents, the hole scavenger concentration, and catalyst loading on the performance of the optimized composite.

Original languageEnglish
Pages (from-to)4550-4557
Number of pages8
Issue number18
Publication statusPublished - 2020 Sept 17

Bibliographical note

Funding Information:
This work was supported by National Research Foundation of Korea (NRF) grants, funded by the Korean Government (MSIP) (2016K1A4A4A01922028 and 2016R1E1A1A01941978). This work was also supported (in part) by the Yonsei University Research Fund (Post Doc. Researcher Supporting Program) of 2019 (project no.: 2019‐12‐0137).

Publisher Copyright:
© 2020 Wiley-VCH GmbH

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry


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