Influence of host lattice on the chemical bonding nature of guest species in high-Tc superconducting I-Bi2Sr1.5-xLa xCa1.5Cu2Oy nanohybrids

Seong Ju Hwang, Dae Hoon Park, Jin Ho Choy

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The influence of the host lattice on the chemical bonding nature of guest iodine species in high-Tc superconducting I - Bi2Sr 1.5-xLaxCa1.5Cu2Oy nanohybrids has been examined by performing combinative X-ray photoelectron spectroscopic (XPS) and X-ray absorption spectroscopic (XAS) analyses. The iodine species were found to possess two kinds of oxidation states, negatively charged iodine (Iδ-) and highly oxidized heptavalent iodine (I+VII). The concentration of heptavalent iodine species is significantly increased by replacing Sr+II ions with La +III ions, indicating that excess oxygen in the host lattice oxidizes the intercalated iodine into heptavalent iodine species. From mass spectroscopic analysis for disintercalated species, it is certain that the heptavalent iodine exists as a periodate IO4- cluster in easily removable sites such as the edge or surface of crystallite. The I L I-edge XAS analyses reveal that even in heavily La-substituted compounds the content of the negatively charged iodide species is still greater than that of the periodate species. The degree of charge transfer between host and guest is also found to depend on La content, which makes it possible to explain the Tc behavior of iodine intercalates with respect to La substitution. The present study provides an intriguing example for the possible control of the bonding nature of guest species through a modification of the composition of the host lattice.

Original languageEnglish
Pages (from-to)12044-12048
Number of pages5
JournalJournal of Physical Chemistry B
Volume108
Issue number32
DOIs
Publication statusPublished - 2004 Aug 12

Fingerprint

Iodine
iodine
X ray absorption
Ions
x rays
Spectroscopic analysis
spectroscopic analysis
Iodides
Photoelectrons
iodides
Charge transfer
ions
photoelectrons
Substitution reactions
charge transfer
substitutes
Oxygen
X rays
Oxidation
oxidation

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films
  • Materials Chemistry

Cite this

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title = "Influence of host lattice on the chemical bonding nature of guest species in high-Tc superconducting I-Bi2Sr1.5-xLa xCa1.5Cu2Oy nanohybrids",
abstract = "The influence of the host lattice on the chemical bonding nature of guest iodine species in high-Tc superconducting I - Bi2Sr 1.5-xLaxCa1.5Cu2Oy nanohybrids has been examined by performing combinative X-ray photoelectron spectroscopic (XPS) and X-ray absorption spectroscopic (XAS) analyses. The iodine species were found to possess two kinds of oxidation states, negatively charged iodine (Iδ-) and highly oxidized heptavalent iodine (I+VII). The concentration of heptavalent iodine species is significantly increased by replacing Sr+II ions with La +III ions, indicating that excess oxygen in the host lattice oxidizes the intercalated iodine into heptavalent iodine species. From mass spectroscopic analysis for disintercalated species, it is certain that the heptavalent iodine exists as a periodate IO4- cluster in easily removable sites such as the edge or surface of crystallite. The I L I-edge XAS analyses reveal that even in heavily La-substituted compounds the content of the negatively charged iodide species is still greater than that of the periodate species. The degree of charge transfer between host and guest is also found to depend on La content, which makes it possible to explain the Tc behavior of iodine intercalates with respect to La substitution. The present study provides an intriguing example for the possible control of the bonding nature of guest species through a modification of the composition of the host lattice.",
author = "Hwang, {Seong Ju} and Park, {Dae Hoon} and Choy, {Jin Ho}",
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Influence of host lattice on the chemical bonding nature of guest species in high-Tc superconducting I-Bi2Sr1.5-xLa xCa1.5Cu2Oy nanohybrids. / Hwang, Seong Ju; Park, Dae Hoon; Choy, Jin Ho.

In: Journal of Physical Chemistry B, Vol. 108, No. 32, 12.08.2004, p. 12044-12048.

Research output: Contribution to journalArticle

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T1 - Influence of host lattice on the chemical bonding nature of guest species in high-Tc superconducting I-Bi2Sr1.5-xLa xCa1.5Cu2Oy nanohybrids

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N2 - The influence of the host lattice on the chemical bonding nature of guest iodine species in high-Tc superconducting I - Bi2Sr 1.5-xLaxCa1.5Cu2Oy nanohybrids has been examined by performing combinative X-ray photoelectron spectroscopic (XPS) and X-ray absorption spectroscopic (XAS) analyses. The iodine species were found to possess two kinds of oxidation states, negatively charged iodine (Iδ-) and highly oxidized heptavalent iodine (I+VII). The concentration of heptavalent iodine species is significantly increased by replacing Sr+II ions with La +III ions, indicating that excess oxygen in the host lattice oxidizes the intercalated iodine into heptavalent iodine species. From mass spectroscopic analysis for disintercalated species, it is certain that the heptavalent iodine exists as a periodate IO4- cluster in easily removable sites such as the edge or surface of crystallite. The I L I-edge XAS analyses reveal that even in heavily La-substituted compounds the content of the negatively charged iodide species is still greater than that of the periodate species. The degree of charge transfer between host and guest is also found to depend on La content, which makes it possible to explain the Tc behavior of iodine intercalates with respect to La substitution. The present study provides an intriguing example for the possible control of the bonding nature of guest species through a modification of the composition of the host lattice.

AB - The influence of the host lattice on the chemical bonding nature of guest iodine species in high-Tc superconducting I - Bi2Sr 1.5-xLaxCa1.5Cu2Oy nanohybrids has been examined by performing combinative X-ray photoelectron spectroscopic (XPS) and X-ray absorption spectroscopic (XAS) analyses. The iodine species were found to possess two kinds of oxidation states, negatively charged iodine (Iδ-) and highly oxidized heptavalent iodine (I+VII). The concentration of heptavalent iodine species is significantly increased by replacing Sr+II ions with La +III ions, indicating that excess oxygen in the host lattice oxidizes the intercalated iodine into heptavalent iodine species. From mass spectroscopic analysis for disintercalated species, it is certain that the heptavalent iodine exists as a periodate IO4- cluster in easily removable sites such as the edge or surface of crystallite. The I L I-edge XAS analyses reveal that even in heavily La-substituted compounds the content of the negatively charged iodide species is still greater than that of the periodate species. The degree of charge transfer between host and guest is also found to depend on La content, which makes it possible to explain the Tc behavior of iodine intercalates with respect to La substitution. The present study provides an intriguing example for the possible control of the bonding nature of guest species through a modification of the composition of the host lattice.

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