Influence of iron precursors on catalytic wet oxidation of H2S to sulfur over Fe/MgO catalysts

Eun Ku Lee; Kwang Deog Jung; Oh Shim Joo; Yong Gun Shul

doi:10.1016/j.molcata.2005.05.034

Influence of iron precursors on catalytic wet oxidation of H₂S to sulfur over Fe/MgO catalysts

Eun Ku Lee, Kwang Deog Jung, Oh Shim Joo, Yong Gun Shul

Department of Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article

11 Citations (Scopus)

Abstract

The Fe/MgO catalysts prepared from iron nitrate, iron chloride and iron sulfate were studied for catalytic wet oxidation of H₂S to sulfur. They were characterized using BET, XRD, H₂-TPR and TG/DSC techniques. Catalysts prepared from iron nitrate showed the highest H₂S removal ability among the prepared catalysts. Both the TPR and XPS analyses of the catalysts indicate that H₂S removal ability correlates with the dispersion of iron oxide in the Fe/MgO catalysts prepared from different iron precursors.

Original language	English
Pages (from-to)	64-67
Number of pages	4
Journal	Journal of Molecular Catalysis A: Chemical
Volume	239
Issue number	1-2
DOIs	https://doi.org/10.1016/j.molcata.2005.05.034
Publication status	Published - 2005 Sep 14

All Science Journal Classification (ASJC) codes

Catalysis
Process Chemistry and Technology
Physical and Theoretical Chemistry

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title = "Influence of iron precursors on catalytic wet oxidation of H2S to sulfur over Fe/MgO catalysts",

abstract = "The Fe/MgO catalysts prepared from iron nitrate, iron chloride and iron sulfate were studied for catalytic wet oxidation of H2S to sulfur. They were characterized using BET, XRD, H2-TPR and TG/DSC techniques. Catalysts prepared from iron nitrate showed the highest H2S removal ability among the prepared catalysts. Both the TPR and XPS analyses of the catalysts indicate that H2S removal ability correlates with the dispersion of iron oxide in the Fe/MgO catalysts prepared from different iron precursors.",

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T1 - Influence of iron precursors on catalytic wet oxidation of H2S to sulfur over Fe/MgO catalysts

AU - Lee, Eun Ku

AU - Jung, Kwang Deog

AU - Joo, Oh Shim

AU - Shul, Yong Gun

PY - 2005/9/14

Y1 - 2005/9/14

N2 - The Fe/MgO catalysts prepared from iron nitrate, iron chloride and iron sulfate were studied for catalytic wet oxidation of H2S to sulfur. They were characterized using BET, XRD, H2-TPR and TG/DSC techniques. Catalysts prepared from iron nitrate showed the highest H2S removal ability among the prepared catalysts. Both the TPR and XPS analyses of the catalysts indicate that H2S removal ability correlates with the dispersion of iron oxide in the Fe/MgO catalysts prepared from different iron precursors.

AB - The Fe/MgO catalysts prepared from iron nitrate, iron chloride and iron sulfate were studied for catalytic wet oxidation of H2S to sulfur. They were characterized using BET, XRD, H2-TPR and TG/DSC techniques. Catalysts prepared from iron nitrate showed the highest H2S removal ability among the prepared catalysts. Both the TPR and XPS analyses of the catalysts indicate that H2S removal ability correlates with the dispersion of iron oxide in the Fe/MgO catalysts prepared from different iron precursors.

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JO - Journal of Molecular Catalysis A: Chemical

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