Influence of the oxygen partial pressure and the boron content on the behavior of boron in calcium silicate melts

Sunghee Lee; Eun Jin Jung; Joo Hyun Park; Dong Joon Min

doi:10.1016/j.jnoncrysol.2015.08.033

Influence of the oxygen partial pressure and the boron content on the behavior of boron in calcium silicate melts

Sunghee Lee, Eun Jin Jung, Joo Hyun Park, Dong Joon Min

Department of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The dissolution behavior of boron in a molten slag was evaluated at 1823 K to establish the boron refining mechanism. From the thermodynamic consideration, two refining mechanisms are confirmed, and a modified equation is suggested. In addition, the structural characteristics of boron in molten slag in different oxygen partial pressure were evaluated to confirm the boride and borate behaviors. The changes in ionic state of boron caused by the oxygen partial pressure were confirmed via Raman spectroscopy. In addition, the network forming characteristics of borate and the network modifying characteristics of boride were observed. From the above results, to improve the boron refinement and the slag fluidity, thereby preventing the silicon loss, refinement of the boron through a slag having much lower equilibrium oxygen partial pressure is suggested.

Original language	English
Pages (from-to)	54-60
Number of pages	7
Journal	Journal of Non-Crystalline Solids
Volume	429
DOIs	https://doi.org/10.1016/j.jnoncrysol.2015.08.033
Publication status	Published - 2015 Dec 1

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Materials Chemistry

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title = "Influence of the oxygen partial pressure and the boron content on the behavior of boron in calcium silicate melts",

abstract = "The dissolution behavior of boron in a molten slag was evaluated at 1823 K to establish the boron refining mechanism. From the thermodynamic consideration, two refining mechanisms are confirmed, and a modified equation is suggested. In addition, the structural characteristics of boron in molten slag in different oxygen partial pressure were evaluated to confirm the boride and borate behaviors. The changes in ionic state of boron caused by the oxygen partial pressure were confirmed via Raman spectroscopy. In addition, the network forming characteristics of borate and the network modifying characteristics of boride were observed. From the above results, to improve the boron refinement and the slag fluidity, thereby preventing the silicon loss, refinement of the boron through a slag having much lower equilibrium oxygen partial pressure is suggested.",

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T1 - Influence of the oxygen partial pressure and the boron content on the behavior of boron in calcium silicate melts

AU - Lee, Sunghee

AU - Jung, Eun Jin

AU - Park, Joo Hyun

AU - Min, Dong Joon

PY - 2015/12/1

Y1 - 2015/12/1

N2 - The dissolution behavior of boron in a molten slag was evaluated at 1823 K to establish the boron refining mechanism. From the thermodynamic consideration, two refining mechanisms are confirmed, and a modified equation is suggested. In addition, the structural characteristics of boron in molten slag in different oxygen partial pressure were evaluated to confirm the boride and borate behaviors. The changes in ionic state of boron caused by the oxygen partial pressure were confirmed via Raman spectroscopy. In addition, the network forming characteristics of borate and the network modifying characteristics of boride were observed. From the above results, to improve the boron refinement and the slag fluidity, thereby preventing the silicon loss, refinement of the boron through a slag having much lower equilibrium oxygen partial pressure is suggested.

AB - The dissolution behavior of boron in a molten slag was evaluated at 1823 K to establish the boron refining mechanism. From the thermodynamic consideration, two refining mechanisms are confirmed, and a modified equation is suggested. In addition, the structural characteristics of boron in molten slag in different oxygen partial pressure were evaluated to confirm the boride and borate behaviors. The changes in ionic state of boron caused by the oxygen partial pressure were confirmed via Raman spectroscopy. In addition, the network forming characteristics of borate and the network modifying characteristics of boride were observed. From the above results, to improve the boron refinement and the slag fluidity, thereby preventing the silicon loss, refinement of the boron through a slag having much lower equilibrium oxygen partial pressure is suggested.

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