Inter-diffused ordered bulk heterojunction organic photovoltaics

Optimized morphology for efficient exciton dissociation and charge transport

Buyoung Jung, Kangmin Kim, Jungwon Kim, Sehwan Kim, Eunkyoung Kim, Woochul Kim

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Effective control of the morphology can enhance the performance of organic photovoltaics. The morphology of an active layer needs to have a large interfacial area between donors and acceptors for efficient exciton dissociation and continuous, direct charge transport paths to electrodes for high charge transport efficiency. These two requirements are usually contradictory. Here, we propose a morphology that meets these requirements nearly simultaneously, called an inter-diffused ordered bulk heterojunction (IDOBHJ). This novel structure exhibited 9% higher performance based on the Monte Carlo simulation than an optimized disordered bulk heterojunction. The main reasons for superior performance were attributed to the comparable short circuit current density and a higher fill factor. We also implemented the IDOBHJ morphology by the experimental nanoimprint technique combined with thermal annealing process to confirm simulation results. Our experimental results are indeed consistent with the theoretical analysis.

Original languageEnglish
Pages (from-to)675-684
Number of pages10
JournalSolar Energy Materials and Solar Cells
Volume120
Issue numberPART B
DOIs
Publication statusPublished - 2014 Jan 1

Fingerprint

Excitons
Heterojunctions
Charge transfer
Short circuit currents
Current density
Annealing
Electrodes
LDS 751

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Surfaces, Coatings and Films

Cite this

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Inter-diffused ordered bulk heterojunction organic photovoltaics : Optimized morphology for efficient exciton dissociation and charge transport. / Jung, Buyoung; Kim, Kangmin; Kim, Jungwon; Kim, Sehwan; Kim, Eunkyoung; Kim, Woochul.

In: Solar Energy Materials and Solar Cells, Vol. 120, No. PART B, 01.01.2014, p. 675-684.

Research output: Contribution to journalArticle

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