Intercalation of gas molecules in graphene oxide interlayer: The role of water

Daeok Kim, Dae Woo Kim, Hyung Kyu Lim, Jiwon Jeon, Hyungjun Kim, Hee Tae Jung, Huen Lee

Research output: Contribution to journalArticle

51 Citations (Scopus)

Abstract

Intercalation phenomena of gas molecules in the interlayer of graphene oxide have been investigated using CO2, CH4, H 2, and N2 gases. Intercalation of gas molecules is highly affected by the affinity between the hydrophilic surface of GO and target molecules. Among tested gases, CO2 can only be intercalated. Furthermore, the swelling of interlayer changed the intercalation phenomena. Amounts of intercalated gases are significantly enhanced, and all the gases can be intercalated by retarded dynamics of intercalated water.

Original languageEnglish
Pages (from-to)11142-11148
Number of pages7
JournalJournal of Physical Chemistry C
Volume118
Issue number20
DOIs
Publication statusPublished - 2014 May 22

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Graphite
Intercalation
intercalation
Oxides
Graphene
interlayers
graphene
Gases
Molecules
oxides
Water
gases
water
molecules
swelling
Swelling
affinity

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Energy(all)
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films

Cite this

Kim, Daeok ; Kim, Dae Woo ; Lim, Hyung Kyu ; Jeon, Jiwon ; Kim, Hyungjun ; Jung, Hee Tae ; Lee, Huen. / Intercalation of gas molecules in graphene oxide interlayer : The role of water. In: Journal of Physical Chemistry C. 2014 ; Vol. 118, No. 20. pp. 11142-11148.
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Intercalation of gas molecules in graphene oxide interlayer : The role of water. / Kim, Daeok; Kim, Dae Woo; Lim, Hyung Kyu; Jeon, Jiwon; Kim, Hyungjun; Jung, Hee Tae; Lee, Huen.

In: Journal of Physical Chemistry C, Vol. 118, No. 20, 22.05.2014, p. 11142-11148.

Research output: Contribution to journalArticle

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