Intercalation route to novel superconducting nano-hybrids

Jin Ho Choy, Woo Lee, Eue Soon Jang, Soon Jae Kwon, Seong Ju Hwang, Young Il Kim

Research output: Contribution to journalConference article

3 Citations (Scopus)

Abstract

We have adopted novel synthetic strategies, i.e. HSAB (hard-soft-acid-base) interaction and interlayer complexation concepts, to develop the superconducting nano-hybrids via intercalation technique. On the basis of these concepts, new series of inorganic-inorganic nano-hybrids, M-X-Bi 2 Sr 2 Ca n-1 Cu n O y (M = Hg, Ag, Au; X = Br, I; n = 1, 2, and 3) and of organic-inorganic ones, R 2 HgI 4 -Bi 2 Sr 2 Ca n-1 Cu n O y (R = organic cation) could be successfully prepared. The magnetic susceptibility measurements for these intercalates reveal that the intercalation of organic chain molecules has little influence on the superconducting transition temperature (T c ) of the pristine compounds, in spite of remarkable basal increments up to approximately 30 angstroms. It has been also demonstrated that the present organic intercalates can be used as effective precursor materials for fabricating the superconducting thin film and nano-particle.

Original languageEnglish
Pages (from-to)479-484
Number of pages6
JournalMolecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume341
DOIs
Publication statusPublished - 2000 Jan 1
Event10th International Symposium on Intercalation Compounds (ISIC 10) - Okasaki, Jpn
Duration: 1999 May 301999 Jun 3

Fingerprint

Intercalation
intercalation
routes
Superconducting films
Complexation
Magnetic susceptibility
Superconducting transition temperature
Cations
interlayers
Positive ions
transition temperature
magnetic permeability
cations
acids
Molecules
Acids
thin films
molecules
interactions

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics

Cite this

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title = "Intercalation route to novel superconducting nano-hybrids",
abstract = "We have adopted novel synthetic strategies, i.e. HSAB (hard-soft-acid-base) interaction and interlayer complexation concepts, to develop the superconducting nano-hybrids via intercalation technique. On the basis of these concepts, new series of inorganic-inorganic nano-hybrids, M-X-Bi 2 Sr 2 Ca n-1 Cu n O y (M = Hg, Ag, Au; X = Br, I; n = 1, 2, and 3) and of organic-inorganic ones, R 2 HgI 4 -Bi 2 Sr 2 Ca n-1 Cu n O y (R = organic cation) could be successfully prepared. The magnetic susceptibility measurements for these intercalates reveal that the intercalation of organic chain molecules has little influence on the superconducting transition temperature (T c ) of the pristine compounds, in spite of remarkable basal increments up to approximately 30 angstroms. It has been also demonstrated that the present organic intercalates can be used as effective precursor materials for fabricating the superconducting thin film and nano-particle.",
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Intercalation route to novel superconducting nano-hybrids. / Choy, Jin Ho; Lee, Woo; Jang, Eue Soon; Kwon, Soon Jae; Hwang, Seong Ju; Kim, Young Il.

In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, Vol. 341, 01.01.2000, p. 479-484.

Research output: Contribution to journalConference article

TY - JOUR

T1 - Intercalation route to novel superconducting nano-hybrids

AU - Choy, Jin Ho

AU - Lee, Woo

AU - Jang, Eue Soon

AU - Kwon, Soon Jae

AU - Hwang, Seong Ju

AU - Kim, Young Il

PY - 2000/1/1

Y1 - 2000/1/1

N2 - We have adopted novel synthetic strategies, i.e. HSAB (hard-soft-acid-base) interaction and interlayer complexation concepts, to develop the superconducting nano-hybrids via intercalation technique. On the basis of these concepts, new series of inorganic-inorganic nano-hybrids, M-X-Bi 2 Sr 2 Ca n-1 Cu n O y (M = Hg, Ag, Au; X = Br, I; n = 1, 2, and 3) and of organic-inorganic ones, R 2 HgI 4 -Bi 2 Sr 2 Ca n-1 Cu n O y (R = organic cation) could be successfully prepared. The magnetic susceptibility measurements for these intercalates reveal that the intercalation of organic chain molecules has little influence on the superconducting transition temperature (T c ) of the pristine compounds, in spite of remarkable basal increments up to approximately 30 angstroms. It has been also demonstrated that the present organic intercalates can be used as effective precursor materials for fabricating the superconducting thin film and nano-particle.

AB - We have adopted novel synthetic strategies, i.e. HSAB (hard-soft-acid-base) interaction and interlayer complexation concepts, to develop the superconducting nano-hybrids via intercalation technique. On the basis of these concepts, new series of inorganic-inorganic nano-hybrids, M-X-Bi 2 Sr 2 Ca n-1 Cu n O y (M = Hg, Ag, Au; X = Br, I; n = 1, 2, and 3) and of organic-inorganic ones, R 2 HgI 4 -Bi 2 Sr 2 Ca n-1 Cu n O y (R = organic cation) could be successfully prepared. The magnetic susceptibility measurements for these intercalates reveal that the intercalation of organic chain molecules has little influence on the superconducting transition temperature (T c ) of the pristine compounds, in spite of remarkable basal increments up to approximately 30 angstroms. It has been also demonstrated that the present organic intercalates can be used as effective precursor materials for fabricating the superconducting thin film and nano-particle.

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