TY - JOUR
T1 - Interconversion between μ-η2,η2-C60 and μ3-η2,η2,η2C60 on a carbido pentaosmium cluster framework
AU - Lee, Kwangyeol
AU - Lee, Chang Hoon
AU - Song, Hyunjoon
AU - Park, Joon T.
AU - Chang, Hong Young
AU - Choi, Moon Gun
PY - 2000/5/15
Y1 - 2000/5/15
N2 - Carbonyl addition or elimination reactions on an Os5C cluster framework result in a novel interconversion between two C60 bonding modes: μ3- η2,η2,η2-C60 for 1 and μ-η2,η2-C60 for 2. The latter bonding mode had been elusive until now, and treatment of 1 with BnNC and subsequent thermolysis provides yet another example, 3. The μ-η2,η2-C60 ligand exhibits two different orientations with respect to the Os3 face in 2 and 3.
AB - Carbonyl addition or elimination reactions on an Os5C cluster framework result in a novel interconversion between two C60 bonding modes: μ3- η2,η2,η2-C60 for 1 and μ-η2,η2-C60 for 2. The latter bonding mode had been elusive until now, and treatment of 1 with BnNC and subsequent thermolysis provides yet another example, 3. The μ-η2,η2-C60 ligand exhibits two different orientations with respect to the Os3 face in 2 and 3.
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U2 - 10.1002/(SICI)1521-3773(20000515)39:10<1801::AID-ANIE1801>3.0.CO;2-L
DO - 10.1002/(SICI)1521-3773(20000515)39:10<1801::AID-ANIE1801>3.0.CO;2-L
M3 - Article
AN - SCOPUS:0039965058
SN - 1433-7851
VL - 39
SP - 1801
EP - 1804
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 10
ER -