Inverted sapphyrin: A new family of doubly N-confused expanded porphyrins

Jonathan L. Sessler; Dong Gyu Cho; Marcin Stȩpień; Vincent Lynch; Jacek Waluk; Zin Seok Yoon; Dongho Kim

doi:10.1021/ja064675z

Inverted sapphyrin: A new family of doubly N-confused expanded porphyrins

Jonathan L. Sessler, Dong Gyu Cho, Marcin Stȩpień, Vincent Lynch, Jacek Waluk, Zin Seok Yoon, Dongho Kim

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

62 Citations (Scopus)

Abstract

The synthesis of an inverted, methoxylated sapphyrin derivative is described. This system, wherein inversion of pyrrolic nitrogen atoms is configurationally enforced via the use of a 3,3′-bipyrrolic precursor, displays what is best described as "weak aromaticity" as judged from its spectroscopic features and supporting theoretical calculations.

Original language	English
Pages (from-to)	12640-12641
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	128
Issue number	39
DOIs	https://doi.org/10.1021/ja064675z
Publication status	Published - 2006 Oct 4

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

Access to Document

10.1021/ja064675z

Cite this

@article{1e920feac1a14ac99ae7780cdad899f5,

title = "Inverted sapphyrin: A new family of doubly N-confused expanded porphyrins",

abstract = "The synthesis of an inverted, methoxylated sapphyrin derivative is described. This system, wherein inversion of pyrrolic nitrogen atoms is configurationally enforced via the use of a 3,3′-bipyrrolic precursor, displays what is best described as {"}weak aromaticity{"} as judged from its spectroscopic features and supporting theoretical calculations.",

author = "Sessler, {Jonathan L.} and Cho, {Dong Gyu} and Marcin Stȩpie{\'n} and Vincent Lynch and Jacek Waluk and Yoon, {Zin Seok} and Dongho Kim",

year = "2006",

month = oct,

day = "4",

doi = "10.1021/ja064675z",

language = "English",

volume = "128",

pages = "12640--12641",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "39",

}

TY - JOUR

T1 - Inverted sapphyrin

T2 - A new family of doubly N-confused expanded porphyrins

AU - Sessler, Jonathan L.

AU - Cho, Dong Gyu

AU - Stȩpień, Marcin

AU - Lynch, Vincent

AU - Waluk, Jacek

AU - Yoon, Zin Seok

AU - Kim, Dongho

PY - 2006/10/4

Y1 - 2006/10/4

N2 - The synthesis of an inverted, methoxylated sapphyrin derivative is described. This system, wherein inversion of pyrrolic nitrogen atoms is configurationally enforced via the use of a 3,3′-bipyrrolic precursor, displays what is best described as "weak aromaticity" as judged from its spectroscopic features and supporting theoretical calculations.

AB - The synthesis of an inverted, methoxylated sapphyrin derivative is described. This system, wherein inversion of pyrrolic nitrogen atoms is configurationally enforced via the use of a 3,3′-bipyrrolic precursor, displays what is best described as "weak aromaticity" as judged from its spectroscopic features and supporting theoretical calculations.

UR - http://www.scopus.com/inward/record.url?scp=33749537089&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33749537089&partnerID=8YFLogxK

U2 - 10.1021/ja064675z

DO - 10.1021/ja064675z

M3 - Article

C2 - 17002345

AN - SCOPUS:33749537089

SN - 0002-7863

VL - 128

SP - 12640

EP - 12641

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 39

ER -

Inverted sapphyrin: A new family of doubly N-confused expanded porphyrins

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this