Inverted sapphyrin: A new family of doubly N-confused expanded porphyrins

Jonathan L. Sessler, Dong Gyu Cho, Marcin Stȩpień, Vincent Lynch, Jacek Waluk, Zin Seok Yoon, Dongho Kim

Research output: Contribution to journalArticlepeer-review

55 Citations (Scopus)

Abstract

The synthesis of an inverted, methoxylated sapphyrin derivative is described. This system, wherein inversion of pyrrolic nitrogen atoms is configurationally enforced via the use of a 3,3′-bipyrrolic precursor, displays what is best described as "weak aromaticity" as judged from its spectroscopic features and supporting theoretical calculations.

Original languageEnglish
Pages (from-to)12640-12641
Number of pages2
JournalJournal of the American Chemical Society
Volume128
Issue number39
DOIs
Publication statusPublished - 2006 Oct 4

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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