Ir(I)/HCl catalyzed head-to-tail homocoupling reactions of vinylsilanes

Jung Woo Park; Sung Joon Park; Chul Ho Jun

doi:10.1021/ol300203w

Ir(I)/HCl catalyzed head-to-tail homocoupling reactions of vinylsilanes

Jung Woo Park, Sung Joon Park, Chul Ho Jun

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Novel homocoupling reactions of vinylsilanes, catalyzed by a mixture of Ir(I) and HCl, were developed. This process leads to exclusive formation of head-to-tail vinylsilane dimers in high yields at room temperature. Synthetic attributes of transformations of the resulting head-to-tail vinylsilane dimers and polymerization of bis(vinylsilane) were investigated.

Original language	English
Pages (from-to)	1468-1471
Number of pages	4
Journal	Organic Letters
Volume	14
Issue number	6
DOIs	https://doi.org/10.1021/ol300203w
Publication status	Published - 2012 Mar 16

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol300203w

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title = "Ir(I)/HCl catalyzed head-to-tail homocoupling reactions of vinylsilanes",

abstract = "Novel homocoupling reactions of vinylsilanes, catalyzed by a mixture of Ir(I) and HCl, were developed. This process leads to exclusive formation of head-to-tail vinylsilane dimers in high yields at room temperature. Synthetic attributes of transformations of the resulting head-to-tail vinylsilane dimers and polymerization of bis(vinylsilane) were investigated.",

author = "Park, {Jung Woo} and Park, {Sung Joon} and Jun, {Chul Ho}",

year = "2012",

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AU - Park, Jung Woo

AU - Park, Sung Joon

AU - Jun, Chul Ho

PY - 2012/3/16

Y1 - 2012/3/16

N2 - Novel homocoupling reactions of vinylsilanes, catalyzed by a mixture of Ir(I) and HCl, were developed. This process leads to exclusive formation of head-to-tail vinylsilane dimers in high yields at room temperature. Synthetic attributes of transformations of the resulting head-to-tail vinylsilane dimers and polymerization of bis(vinylsilane) were investigated.

AB - Novel homocoupling reactions of vinylsilanes, catalyzed by a mixture of Ir(I) and HCl, were developed. This process leads to exclusive formation of head-to-tail vinylsilane dimers in high yields at room temperature. Synthetic attributes of transformations of the resulting head-to-tail vinylsilane dimers and polymerization of bis(vinylsilane) were investigated.

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JO - Organic Letters

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Ir(I)/HCl catalyzed head-to-tail homocoupling reactions of vinylsilanes

Abstract

All Science Journal Classification (ASJC) codes

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