Isoxazole-Based Electrolytes for Lithium Metal Protection and Lithium-Sulfurized Polyacrylonitrile (SPAN) Battery Operating at Low Temperature

Sha Tan; Haodong Liu; Zhaohui Wu; Conan Weiland; Seong Min Bak; Arthur Ronne; Ping Liu; M. Stanley Whittingham; Zulipiya Shadike; Enyuan Hu; Xiao Qing Yang

doi:10.1149/1945-7111/ac58c5

Isoxazole-Based Electrolytes for Lithium Metal Protection and Lithium-Sulfurized Polyacrylonitrile (SPAN) Battery Operating at Low Temperature

Sha Tan, Haodong Liu, Zhaohui Wu, Conan Weiland, Seong Min Bak, Arthur Ronne, Ping Liu, M. Stanley Whittingham, Zulipiya Shadike, Enyuan Hu, Xiao Qing Yang

Department of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

A new electrolyte system using isoxazole as the salt dissolving solvent has been developed and studied for lithium metal batteries. By using fluoroethylene carbonate (FEC) as an additive and 1,1,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoropropyl ether (TTE) as a diluent for localized high concentration electrolyte (LHCE), isoxazole-based electrolytes were successfully implemented in lithium metal batteries, demonstrating excellent lithium metal protection capability. Utilizing several advanced characterization techniques (including synchrotron-based X-ray absorption spectroscopy and photoelectron spectroscopy), the solid electrolyte interphase (SEI) formed on the Li-metal anode after employing these electrolytes was thoroughly investigated. The high ionic conductivity of isoxazole at low temperature and the low impedance of SEI formed in LHCE significantly improved the low-temperature performance of Li-sulfurized polyacrylonitrile (SPAN) batteries, delivering 273.8 mAh g-1 capacity at -30 °C with 99.85% capacity retention after 50 cycles.

Original language	English
Article number	030513
Journal	Journal of the Electrochemical Society
Volume	169
Issue number	3
DOIs	https://doi.org/10.1149/1945-7111/ac58c5
Publication status	Published - 2022 Mar

Bibliographical note

Funding Information:
The work done at Brookhaven National Laboratory was supported by the Assistant Secretary for Energy Efficiency and Renewable Energy, Vehicle Technology Office of the US Department of Energy (DOE) through the Advanced Battery Materials Research (BMR) Program, including Battery500 Consortium under contract no. DE-SC0012704. This work at University of California San Diego was supported by the Office of Vehicle Technologies of the U.S. Department of Energy through the Advanced Battery Materials Research (BMR) Program (Battery500 Consortium) under Contract no. DE-EE0007764. This research used beamline 8-BM (TES) and 7-ID-2 (SST-2) of the National Synchrotron Light Source II, U.S. DOE Office of Science User Facilities, operated for the DOE Office of Science by Brookhaven National Laboratory under contract no. DE-SC0012704. SEM measurements for this manuscript were performed at Center for Functional Nanomaterials, a U.S. DOE office of Science User Facility, at Brookhaven National Laboratory under the contract no. DE-SC0012704. Prof. S. Whittingham is supported by the Assistant Secretary for Energy Efficiency and Renewable Energy, Vehicle Technology Office of the U.S. DOE through the Advanced Battery Materials Research (BMR) Program, including Battery500 Consortium under contract No. DE-EE0007765.

Publisher Copyright:
© 2022 The Author(s). Published on behalf of The Electrochemical Society by IOP Publishing Limited.

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Renewable Energy, Sustainability and the Environment
Surfaces, Coatings and Films
Electrochemistry
Materials Chemistry

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This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1149/1945-7111/ac58c5

Cite this

Tan, S., Liu, H., Wu, Z., Weiland, C., Bak, S. M., Ronne, A., Liu, P., Whittingham, M. S., Shadike, Z., Hu, E., & Yang, X. Q. (2022). Isoxazole-Based Electrolytes for Lithium Metal Protection and Lithium-Sulfurized Polyacrylonitrile (SPAN) Battery Operating at Low Temperature. Journal of the Electrochemical Society, 169(3), [030513]. https://doi.org/10.1149/1945-7111/ac58c5

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abstract = "A new electrolyte system using isoxazole as the salt dissolving solvent has been developed and studied for lithium metal batteries. By using fluoroethylene carbonate (FEC) as an additive and 1,1,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoropropyl ether (TTE) as a diluent for localized high concentration electrolyte (LHCE), isoxazole-based electrolytes were successfully implemented in lithium metal batteries, demonstrating excellent lithium metal protection capability. Utilizing several advanced characterization techniques (including synchrotron-based X-ray absorption spectroscopy and photoelectron spectroscopy), the solid electrolyte interphase (SEI) formed on the Li-metal anode after employing these electrolytes was thoroughly investigated. The high ionic conductivity of isoxazole at low temperature and the low impedance of SEI formed in LHCE significantly improved the low-temperature performance of Li-sulfurized polyacrylonitrile (SPAN) batteries, delivering 273.8 mAh g-1 capacity at -30 °C with 99.85% capacity retention after 50 cycles.",

author = "Sha Tan and Haodong Liu and Zhaohui Wu and Conan Weiland and Bak, {Seong Min} and Arthur Ronne and Ping Liu and Whittingham, {M. Stanley} and Zulipiya Shadike and Enyuan Hu and Yang, {Xiao Qing}",

note = "Funding Information: The work done at Brookhaven National Laboratory was supported by the Assistant Secretary for Energy Efficiency and Renewable Energy, Vehicle Technology Office of the US Department of Energy (DOE) through the Advanced Battery Materials Research (BMR) Program, including Battery500 Consortium under contract no. DE-SC0012704. This work at University of California San Diego was supported by the Office of Vehicle Technologies of the U.S. Department of Energy through the Advanced Battery Materials Research (BMR) Program (Battery500 Consortium) under Contract no. DE-EE0007764. This research used beamline 8-BM (TES) and 7-ID-2 (SST-2) of the National Synchrotron Light Source II, U.S. DOE Office of Science User Facilities, operated for the DOE Office of Science by Brookhaven National Laboratory under contract no. DE-SC0012704. SEM measurements for this manuscript were performed at Center for Functional Nanomaterials, a U.S. DOE office of Science User Facility, at Brookhaven National Laboratory under the contract no. DE-SC0012704. Prof. S. Whittingham is supported by the Assistant Secretary for Energy Efficiency and Renewable Energy, Vehicle Technology Office of the U.S. DOE through the Advanced Battery Materials Research (BMR) Program, including Battery500 Consortium under contract No. DE-EE0007765. Publisher Copyright: {\textcopyright} 2022 The Author(s). Published on behalf of The Electrochemical Society by IOP Publishing Limited.",

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AU - Whittingham, M. Stanley

AU - Shadike, Zulipiya

AU - Hu, Enyuan

AU - Yang, Xiao Qing

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N2 - A new electrolyte system using isoxazole as the salt dissolving solvent has been developed and studied for lithium metal batteries. By using fluoroethylene carbonate (FEC) as an additive and 1,1,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoropropyl ether (TTE) as a diluent for localized high concentration electrolyte (LHCE), isoxazole-based electrolytes were successfully implemented in lithium metal batteries, demonstrating excellent lithium metal protection capability. Utilizing several advanced characterization techniques (including synchrotron-based X-ray absorption spectroscopy and photoelectron spectroscopy), the solid electrolyte interphase (SEI) formed on the Li-metal anode after employing these electrolytes was thoroughly investigated. The high ionic conductivity of isoxazole at low temperature and the low impedance of SEI formed in LHCE significantly improved the low-temperature performance of Li-sulfurized polyacrylonitrile (SPAN) batteries, delivering 273.8 mAh g-1 capacity at -30 °C with 99.85% capacity retention after 50 cycles.

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Isoxazole-Based Electrolytes for Lithium Metal Protection and Lithium-Sulfurized Polyacrylonitrile (SPAN) Battery Operating at Low Temperature

Abstract

Bibliographical note

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