Kinetic separation of propene and propane in metal-organic frameworks: Controlling diffusion rates in plate-shaped crystals via tuning of pore apertures and crystallite aspect ratios

Chang Yeon Lee, Youn Sang Bae, Nak Cheon Jeong, Omar K. Farha, Amy A. Sarjeant, Charlotte L. Stern, Peter Nickias, Randall Q. Snurr, Joseph T. Hupp, Sonbinh T. Nguyen

Research output: Contribution to journalArticle

152 Citations (Scopus)

Abstract

A series of isostructural, noncatenated, zinc-pillared-paddlewheel metal-organic framework materials has been synthesized from 1,2,4,5- tetrakis(carboxyphenyl)benzene and trans-1,2-dipyridylethene struts. Substantial kinetic selectivity in the adsorption of propene over propane can be observed, depending on the pore apertures and the rectangular-plate morphology of the crystals.(Figure Presented)

Original languageEnglish
Pages (from-to)5228-5231
Number of pages4
JournalJournal of the American Chemical Society
Volume133
Issue number14
DOIs
Publication statusPublished - 2011 Apr 13

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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